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- W2086752463 abstract "Acid-Catalyzed Reactions of 2-Vinylaniline Derivatives with 1-Benzyl- and 1-Methylpiperidin-4-one: An Elegant Synthesis of New Polycyclic Indole Derivatives The reaction of 2-vinylaniline derivatives with 1-benzylpiperidin-4-one or 1-methylpiperidin-4-one in toluene at temperatures between 115 and 120° with toluene-4-sulfonic acid as catalyst leads in good yields to a new class of polycyclic indole derivatives (Scheme 1, Table 1). The structure of the new diastereoisomerically pure racemic compounds 1–5 is determined by NMR-spectroscopic methods. A reaction mechanism proceeding via cyclization of enamine 9, leading to a racemic, tricyclic reactive intermediate 10, and subsequent intramolecular 1,5-dipolar cyclization as key steps in proposed for the formation of octahydropyrido[4′,3′:4]cyclobut[1,2-b]indoles 1–5. The scope and limitations of the new method are discussed (see Table 2)." @default.
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- W2086752463 date "1993-06-30" @default.
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- W2086752463 title "Säurekatalysierte Umsetzungen von 2- Vinylanilin-Derivaten mit 1-Benzyl- und 1-Methylpiperidin-4-on: Eine Elegante Synthese Neuer Polycyclischer Indol-Derivate" @default.
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- W2086752463 doi "https://doi.org/10.1002/hlca.19930760407" @default.
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