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• W2086753604 abstract "The methanol synthesis activity of intermetallic catalysts derived from Zr/Cu and Ti/Cu alloys containing rare earth metals (and yttrium) was investigated in a CO/H2 gas feed at pressures of 12 bar and 50 bar and at temperatures up to 523 K. We have found that the rate of methanol synthesis over both Zr/Cu and Ti/Cu catalysts is substantially increased by the addition of the RE component (RE= rare earth or yttrium). In the most favourable case only 2 atom-% of yttrium was required in an alloy of Zr/Cu to produce a catalyst with a stable methanol synthesis activity of 11 mol/kg/h at 50 bar, 513 K - a 200% improvement. Furthermore, the maximum methanol activity observed for a range of alloys of general composition Zr0.7/RE0.3/Cu2.0 activated at 12 bar was found to be strongly dependent on the ionic radius of the RE component." @default.
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• W2086753604 date "1990-02-01" @default.
• W2086753604 modified "2023-10-07" @default.
• W2086753604 title "Methanol synthesis catalysts derived from ternary rare earth, copper, zirconium and rare earth, copper, titanium intermetallic alloys" @default.
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• W2086753604 doi "https://doi.org/10.1016/s0166-9834(00)82279-4" @default.
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