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- W2086777416 abstract "Fe(CO)a(CsH1004)), Mr=310.0 , mono- clinic, P2Jn, a=11.093(4), b=10.680(3), c= 11.763 (5)A, fl=101.45(3) ° , V=1366(1)A 3, Z= 4, Dx=l.51Mgm -3, MoKa, 2=0.7107,/k, /x= 1.124 mm -x, F(000) -- 632, T= 293 K, R = 0.046 for 1888 observed reflections. The molecular structure is determined from the X-ray data and confirms the structure previously assigned on the basis of IR and NMR spectra. The Fe(CO)3 group is symmetrically bonded to the butadiene moiety formed by C (4) to C (7) of the ligand. Both ester groups at C(4) and C(7) are planar and cis to each other about the central C(5)--C(6) bond. The structure consists of discrete molecules held in the crystal by van der Waals forces. Introduction. As part of our investigations of com- plexes between Fe(CO)3 and vinyl ester ligands, the title compound (1) was synthesized. Several complexes between Fe(CO)3 and the vinyl ligand with various substituents including phenyl, ester and acyl groups" @default.
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- W2086777416 date "1987-11-15" @default.
- W2086777416 modified "2023-10-18" @default.
- W2086777416 title "Structure of tricarbonyl(η4-syn-1,4-diacetoxy-1,3-butadiene)iron(0)" @default.
- W2086777416 doi "https://doi.org/10.1107/s0108270187089005" @default.
- W2086777416 hasPublicationYear "1987" @default.
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