FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2086804631> ?p ?o ?g. }

• W2086804631 endingPage "1498" @default.
• W2086804631 startingPage "1485" @default.
• W2086804631 abstract "The back-electron transfer (b-ET) process in the hexamethylbenzene/tetracyanoethylene charge-transfer complex was studied by the transient absorption spectroscopy in several fluids (ethane, nitrous oxide, carbon dioxide, and trifluoromethane) from the critical density to twice that of it at 323.2 K. The b-ET rate was determined by the decay rate of the excited state absorption. The b-ET rate increased with the increase of solvent density in carbon dioxide and nitrous oxide. The b-ET rate also increased in the order of ethane, nitrous oxide, carbon dioxide, and trifluoromethane, compared at the similar reduced density divided by the solvent critical density. Based on the formulation by Marcus and Jortner, the reaction free energy and the solvent reorganization energy were estimated from the change of the absorption spectrum relative to the gaseous phase spectrum, simply by assuming that the intramolecular reorganization energy does not depend on the solvent density and the species. The reaction free energy and the solvent reorganization energy in fluids obtained in this way were almost linearly correlated, and the density dependence was larger in the lower density region. The b-ET rates in various conditions showed a good correlation with the reaction free energy estimated from the spectral simulation. The b-ET rate showed a significant isotope effect by perdeuteriation of hexamethylbenzene as is predicted by the fluorescence quantum yield [K. Kulinowski et al., J. Phys. Chem. 99, 17715 (1995)], which could not be reproduced by this model." @default.
• W2086804631 created "2016-06-24" @default.
• W2086804631 creator A5000006562 @default.
• W2086804631 creator A5014343463 @default.
• W2086804631 creator A5091743328 @default.
• W2086804631 date "1998-01-22" @default.
• W2086804631 modified "2023-10-01" @default.
• W2086804631 title "Effect of the solvent density and species on the back-electron transfer rate in the hexamethylbenzene/tetracyanoethylene charge-transfer complex" @default.
• W2086804631 cites W1968719859 @default.
• W2086804631 cites W1979930541 @default.
• W2086804631 cites W1983565816 @default.
• W2086804631 cites W1985889445 @default.
• W2086804631 cites W1986053765 @default.
• W2086804631 cites W1987284749 @default.
• W2086804631 cites W1993077149 @default.
• W2086804631 cites W1993678837 @default.
• W2086804631 cites W1994809963 @default.
• W2086804631 cites W1995157259 @default.
• W2086804631 cites W1996314843 @default.
• W2086804631 cites W2001721554 @default.
• W2086804631 cites W2002391740 @default.
• W2086804631 cites W2003955325 @default.
• W2086804631 cites W2006798778 @default.
• W2086804631 cites W2008437101 @default.
• W2086804631 cites W2011540936 @default.
• W2086804631 cites W2012403484 @default.
• W2086804631 cites W2013687596 @default.
• W2086804631 cites W2015941539 @default.
• W2086804631 cites W2017216815 @default.
• W2086804631 cites W2017330874 @default.
• W2086804631 cites W2031904472 @default.
• W2086804631 cites W2036036568 @default.
• W2086804631 cites W2036364037 @default.
• W2086804631 cites W2037523587 @default.
• W2086804631 cites W2038626371 @default.
• W2086804631 cites W2039673509 @default.
• W2086804631 cites W2044111889 @default.
• W2086804631 cites W2048116819 @default.
• W2086804631 cites W2054947925 @default.
• W2086804631 cites W2055275145 @default.
• W2086804631 cites W2056461301 @default.
• W2086804631 cites W2056520309 @default.
• W2086804631 cites W2057210145 @default.
• W2086804631 cites W2058604132 @default.
• W2086804631 cites W2059004290 @default.
• W2086804631 cites W2060172218 @default.
• W2086804631 cites W2061785866 @default.
• W2086804631 cites W2063683790 @default.
• W2086804631 cites W2065701683 @default.
• W2086804631 cites W2070710744 @default.
• W2086804631 cites W2076317405 @default.
• W2086804631 cites W2080987850 @default.
• W2086804631 cites W2081110334 @default.
• W2086804631 cites W2081137209 @default.
• W2086804631 cites W2082662238 @default.
• W2086804631 cites W2085385994 @default.
• W2086804631 cites W2092700896 @default.
• W2086804631 cites W2106010269 @default.
• W2086804631 cites W2152941506 @default.
• W2086804631 cites W2155041806 @default.
• W2086804631 cites W2256699045 @default.
• W2086804631 cites W2323942962 @default.
• W2086804631 cites W2333067672 @default.
• W2086804631 cites W2949099349 @default.
• W2086804631 cites W2952518581 @default.
• W2086804631 cites W2953290869 @default.
• W2086804631 cites W4250710126 @default.
• W2086804631 doi "https://doi.org/10.1063/1.475520" @default.
• W2086804631 hasPublicationYear "1998" @default.
• W2086804631 type Work @default.
• W2086804631 sameAs 2086804631 @default.
• W2086804631 citedByCount "22" @default.
• W2086804631 countsByYear W20868046312012 @default.
• W2086804631 countsByYear W20868046312013 @default.
• W2086804631 countsByYear W20868046312016 @default.
• W2086804631 countsByYear W20868046312018 @default.
• W2086804631 crossrefType "journal-article" @default.
• W2086804631 hasAuthorship W2086804631A5000006562 @default.
• W2086804631 hasAuthorship W2086804631A5014343463 @default.
• W2086804631 hasAuthorship W2086804631A5091743328 @default.
• W2086804631 hasConcept C113196181 @default.
• W2086804631 hasConcept C119824511 @default.
• W2086804631 hasConcept C121332964 @default.
• W2086804631 hasConcept C125287762 @default.
• W2086804631 hasConcept C171001562 @default.
• W2086804631 hasConcept C178790620 @default.
• W2086804631 hasConcept C185592680 @default.
• W2086804631 hasConcept C24890656 @default.
• W2086804631 hasConcept C2776513212 @default.
• W2086804631 hasConcept C2777691172 @default.
• W2086804631 hasConcept C2779768264 @default.
• W2086804631 hasConcept C2780471494 @default.
• W2086804631 hasConcept C32891209 @default.
• W2086804631 hasConcept C62520636 @default.
• W2086804631 hasConcept C75473681 @default.
• W2086804631 hasConcept C91881484 @default.
• W2086804631 hasConcept C95503338 @default.
• W2086804631 hasConceptScore W2086804631C113196181 @default.

• next