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• W2086820571 startingPage "1235" @default.
• W2086820571 abstract "Reaction of VOCl3 with racemic trans-1,2-dithiacyclohexanediyl-2,2′-bis(6-tert-butyl-4-methylphenol) affords the chiral-at-metal vanadium(V) complex [V{(C6H2O-6-tert-Bu-4-Me)2S2C6H10}OCl] (1). The molecular structure of 1 was established by single crystal X-ray diffraction, which shows a cis-α configuration of the ligand around the vanadium center. Upon activation with MAO, 1 was found to be a highly active catalyst for the polymerization of ethylene, but was not active in the polymerization of propene and styrene. The influence of temperature and cocatalyst ratio on polymerization activity was studied." @default.
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• W2086820571 date "2009-04-01" @default.
• W2086820571 modified "2023-10-08" @default.
• W2086820571 title "A vanadium(V) complex with a tetradentate [OSSO]-type bis(phenolato) ligand: Synthesis, structure, and ethylene polymerization activity" @default.
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• W2086820571 doi "https://doi.org/10.1016/j.jorganchem.2008.11.008" @default.
• W2086820571 hasPublicationYear "2009" @default.
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