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- W2086869078 abstract "Abstract The high resolution data on the NF 3 ν 4 and ( ν 4 + ν 2 ) infrared bands and the CF 3 H ν 6 infrared band have been investigated in detail using an l -type resonance calculation computer program. By means of the computer simulation technique, the shapes of the observed P , Q , and R branches are accurately reproduced and the frequencies of all the fine structure “lines” in the P and R branches precisely matched. The analysis has provided accurate values of all the band constants whose determination is not possible from the microwave. The signs of q 4 of NF 3 and q 6 of CF 3 H have been established unambiguously. A band structure investigation has shown that the observed P and R branch “lines” ariseprimarily from clusters of closely spaced P P K ( J ) and R R K ( J ) lines of a given J and that in these bands the peaks of these P and R “lines” generally correspond to the K ⋍ J components of the P P ( J ) and R R ( J ) clusters, respectively. The differences between our values of the band constants and those of previous infrared work are found to be remarkably small. This is explained in terms of the band structure investigation." @default.
- W2086869078 created "2016-06-24" @default.
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- W2086869078 date "1971-07-01" @default.
- W2086869078 modified "2023-09-27" @default.
- W2086869078 title "“Pseudo-parallel” infrared bands of oblate symmetric tops NF3 ν4 and (ν4 + ν2), and CF3Hν6" @default.
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- W2086869078 doi "https://doi.org/10.1016/0022-2852(71)90281-5" @default.
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