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• W2086956711 abstract "Transition metal compounds are well documented to have diverse applications such as in catalysis, light-emitting materials and therapeutics. In the areas of photocatalysis and photodynamic therapy, metal compounds of heavy transition metals are highly sought after because they can give rise to triplet excited states upon photoexcitation. The long lifetimes (more than 1 μs) of the triplet states of transition metal compounds allow for bimolecular reactions/processes such as energy transfer and/or electron transfer to occur. Reactions of triplet excited states of luminescent metal compounds with oxygen in cells may generate reactive oxygen species and/or induce damage to DNA, leading to cell death. This article recaps the recent findings on photochemical and phototoxic properties of luminescent platinum(II) and gold(III) compounds both from the literature and experimental results from our group." @default.
• W2086956711 created "2016-06-24" @default.
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• W2086956711 date "2013-07-28" @default.
• W2086956711 modified "2023-10-07" @default.
• W2086956711 title "Light-induced catalytic and cytotoxic properties of phosphorescent transition metal compounds with a d ⁸ electronic configuration" @default.
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• W2086956711 doi "https://doi.org/10.1098/rsta.2012.0126" @default.
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