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- W2086963303 abstract "An overview of the recently discovered binding of molecular hydrogen (H2) to transition metal complexes is given. Emphasis is placed on the features which distinguish non-classical metal-dihydrogen bonding from classical atomic metal-hydride systems. Crystallographic and spectroscopic data (IR, nuclear magnetic resonance (NMR), inelastic neutron scattering) and theoretical aspects are discussed. The subtle factors which influence cleavage of bound H2 to hydride are identified and examples are given demonstrating that a compound containing a dihydrogen “pair” can exist in facile equilibrium with the “isomeric” compound derived from it containing two separated hydrides. Metal-H2 systems show a uniquely rich dynamic behavior, including rotation of the side-on bonded H2. The relatively low energy barrier to rotation is studied experimentally by inelastic neutron scattering and theoretically by ab initio methods, in relation to the bonding model for M-H2. Quantum mechanical tunneling and exchange processes are identified for bound dihydrogen and certain trihydride systems." @default.
- W2086963303 created "2016-06-24" @default.
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- W2086963303 date "1991-08-01" @default.
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- W2086963303 title "Chemical bonding of hydrogen molecules to transition metal complexes" @default.
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- W2086963303 doi "https://doi.org/10.1016/0022-5088(91)90168-4" @default.
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