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- W2086975213 abstract "The voltammetric behavior of barium and lithium ions in acetonitrile (AN) was studied at polymer membrane ion-selective electrodes which showed Nernstian responses to those metal ions in AN, in order to elucidate the mechanism of their potentiometric responses. The membrane electrodes consisted of polyacrylamide coupled to such poly(oxyethylene) derivatives as tetraethylene glycol monododecyl ether, dibenzo-18-crown-6, and cryptand222B and coated on platinum or gold disk. The cyclic voltammograms for barium and lithium ions, recorded repeatedly after setting the electrodes at the rest potentials, showed a cathodic peak at −1.5±0.2 V vs. Ag/0.01 M Ag+ (AN). The cathodic peak current (icp) decreased markedly between the first and second scans, but reached a steady value after the third scan. The icp values after the third scan were diffusion controlled and considered to be due to a transfer of the metal ions from the solution into the membrane. The differences in icp between the first and the third scans were proportional to the potential scan rate and attributed to a transfer of the metal ions which had been accumulated at or near the surface of the membrane by combining with the functional groups of the polymer. The accumulation occurred rather slowly and saturated with time. Based on the fact that the response processes of the ion-selective electrodes were very much similar to the accumulation processes, the response mechanism of the ion-selective electrodes is discussed." @default.
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- W2086975213 date "1990-09-01" @default.
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- W2086975213 title "Voltammetric Investigation of the Response Mechanism of the Ion-Selective Electrodes Based on the Polymer Modified with Poly(oxyethylene) Derivatives in Acetonitrile" @default.
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- W2086975213 doi "https://doi.org/10.1246/bcsj.63.2615" @default.
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