Matches in SemOpenAlex for { <https://semopenalex.org/work/W2086998540> ?p ?o ?g. }
Showing items 1 to 67 of
67
with 100 items per page.
- W2086998540 endingPage "885" @default.
- W2086998540 startingPage "885" @default.
- W2086998540 abstract "The thermodynamic treatment of charged colloidal systems published recently is applied to solutions in which ionic surfactants bind to macromolecules. The aim is to develop an improved basis for the interpretation of thermodynamic information obtained from techniques such as electromotive-force measurement and dialysis equilibria. The main emphasis is on binding to neutral macromolecules or to polyions with the same sign as the surfactant ions. Expressions are derived which relate the form of binding isotherm to the distribution of bound surfactant ions among the macromolecules and which enable enthalpies of binding to be obtained from the dependence on temperature of the binding equilibria. Several interesting effects are predicted. For example, (a) the average amount bound per macromolecule may decrease with increasing surfactant concentration in the presence of free micelles, (b) the surfactant monomer concentration may exhibit two maxima separated by a minimum, (c) increasing surfactant concentration may cause the macromolecule chemical potential to exhibit two minima separated by a maximum. The theory also explains how observed binding isotherms can be expected to depend on the concentration of macromolecules. The situation in which bound surfactant aggregates coexist with free surfactant aggregates is examined in some detail. The treatment is readily extended to more complex cases such as binding to polyacids and oppositely charged macroions. It is likely to apply equally well to other types of ion binding by macromolecules." @default.
- W2086998540 created "2016-06-24" @default.
- W2086998540 creator A5047999205 @default.
- W2086998540 date "1985-01-01" @default.
- W2086998540 modified "2023-09-26" @default.
- W2086998540 title "Thermodynamics of ionic surfactant binding to macromolecules in solution" @default.
- W2086998540 doi "https://doi.org/10.1039/f19858100885" @default.
- W2086998540 hasPublicationYear "1985" @default.
- W2086998540 type Work @default.
- W2086998540 sameAs 2086998540 @default.
- W2086998540 citedByCount "18" @default.
- W2086998540 countsByYear W20869985402016 @default.
- W2086998540 crossrefType "journal-article" @default.
- W2086998540 hasAuthorship W2086998540A5047999205 @default.
- W2086998540 hasConcept C11268172 @default.
- W2086998540 hasConcept C121332964 @default.
- W2086998540 hasConcept C145148216 @default.
- W2086998540 hasConcept C147789679 @default.
- W2086998540 hasConcept C159467904 @default.
- W2086998540 hasConcept C166940927 @default.
- W2086998540 hasConcept C178790620 @default.
- W2086998540 hasConcept C184651966 @default.
- W2086998540 hasConcept C185592680 @default.
- W2086998540 hasConcept C204389451 @default.
- W2086998540 hasConcept C2182769 @default.
- W2086998540 hasConcept C521977710 @default.
- W2086998540 hasConcept C55493867 @default.
- W2086998540 hasConcept C58226133 @default.
- W2086998540 hasConcept C59789625 @default.
- W2086998540 hasConcept C97355855 @default.
- W2086998540 hasConceptScore W2086998540C11268172 @default.
- W2086998540 hasConceptScore W2086998540C121332964 @default.
- W2086998540 hasConceptScore W2086998540C145148216 @default.
- W2086998540 hasConceptScore W2086998540C147789679 @default.
- W2086998540 hasConceptScore W2086998540C159467904 @default.
- W2086998540 hasConceptScore W2086998540C166940927 @default.
- W2086998540 hasConceptScore W2086998540C178790620 @default.
- W2086998540 hasConceptScore W2086998540C184651966 @default.
- W2086998540 hasConceptScore W2086998540C185592680 @default.
- W2086998540 hasConceptScore W2086998540C204389451 @default.
- W2086998540 hasConceptScore W2086998540C2182769 @default.
- W2086998540 hasConceptScore W2086998540C521977710 @default.
- W2086998540 hasConceptScore W2086998540C55493867 @default.
- W2086998540 hasConceptScore W2086998540C58226133 @default.
- W2086998540 hasConceptScore W2086998540C59789625 @default.
- W2086998540 hasConceptScore W2086998540C97355855 @default.
- W2086998540 hasIssue "4" @default.
- W2086998540 hasLocation W20869985401 @default.
- W2086998540 hasOpenAccess W2086998540 @default.
- W2086998540 hasPrimaryLocation W20869985401 @default.
- W2086998540 hasRelatedWork W1981931605 @default.
- W2086998540 hasRelatedWork W1982761076 @default.
- W2086998540 hasRelatedWork W2050721739 @default.
- W2086998540 hasRelatedWork W2052261042 @default.
- W2086998540 hasRelatedWork W2093495083 @default.
- W2086998540 hasRelatedWork W28890525 @default.
- W2086998540 hasRelatedWork W2949292131 @default.
- W2086998540 hasRelatedWork W3117445210 @default.
- W2086998540 hasRelatedWork W4365513525 @default.
- W2086998540 hasRelatedWork W50554682 @default.
- W2086998540 hasVolume "81" @default.
- W2086998540 isParatext "false" @default.
- W2086998540 isRetracted "false" @default.
- W2086998540 magId "2086998540" @default.
- W2086998540 workType "article" @default.