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- W2087004810 abstract "The abiotic transformation of the halogenated aliphatic compound, 1,1,1-trichloroethane (TCA), to 1,1-dichloroethylene (1,1-DCE) in groundwater was measured in the laboratory at 20°C and neutral pH. The measured pseudo first-order disappearance rate constant for TCA was 0.11 ± 0.16yr−1 (95% confidence interval). The formation rate constant for 1,1-DCE could be determined with greater precision, and was found to be 0.040 ± 0.003 yr-1. These results indicate the 95% confidence interval for TCA half-life at 20°C and pH 7 in homogeneous solution is 2.8 to 19 yrs. While these results confirm that 1,1-DCE is a product from the abiotic transformation of TCA, other products such as acetic acid are also possible, although they were not measured." @default.
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- W2087004810 date "1987-03-01" @default.
- W2087004810 modified "2023-10-14" @default.
- W2087004810 title "Rate of abiotic formation of 1,1-dichloroethylene from 1,1,1-trichloroethane in groundwater" @default.
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- W2087004810 doi "https://doi.org/10.1016/0169-7722(87)90010-6" @default.
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