FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2087016405> ?p ?o ?g. }

• W2087016405 endingPage "9615" @default.
• W2087016405 startingPage "9608" @default.
• W2087016405 abstract "The study of the interaction between xenon and two cryptophane derivatives in organic solution has been carried out through 1H and 129Xe NMR. The cage molecules constituted by the grafting of (−)-camphanic acid are diastereomers through the orientation of the ethylenedioxy linkers joining the cyclotriveratrylene moieties. The availability of laser-polarized xenon has allowed us not only to perform 129Xe spectra at a low concentration of dissolved gas but also to perform magnetization-transfer experiments from xenon to protons, confirming the inclusion of noble gas atoms into the cryptophane cavities. Binding constants of xenon in diastereomers were compared, as well as xenon exchange rates in the cryptophane cavities. A detailed structural and dynamic study performed with help of off-resonance ROESY experiments gave precious local information. The cryptophane derivative with the highest affinity for xenon seems to be the most able to distort its cavity to fit the xenon atom. In the complex, the cavity is elongated, and the noble gas atom can find different locations. This seems to indicate that the entropy contribution is also important in explaining the difference in affinity of xenon between these cage molecules. These results clearly show that in the design of new cage molecules for biosensing, the separation of cryptophane diastereomers is important because their affinity and their properties vis-à-vis xenon can be strongly different." @default.
• W2087016405 created "2016-06-24" @default.
• W2087016405 creator A5003469584 @default.
• W2087016405 creator A5042137930 @default.
• W2087016405 creator A5053704980 @default.
• W2087016405 creator A5056970547 @default.
• W2087016405 creator A5076315023 @default.
• W2087016405 creator A5077734239 @default.
• W2087016405 date "2004-10-13" @default.
• W2087016405 modified "2023-10-02" @default.
• W2087016405 title "NMR Study of Optically Active Monosubstituted Cryptophanes and Their Interaction with Xenon" @default.
• W2087016405 cites W1970970039 @default.
• W2087016405 cites W1979000619 @default.
• W2087016405 cites W1981699679 @default.
• W2087016405 cites W1990502030 @default.
• W2087016405 cites W1993893925 @default.
• W2087016405 cites W2012535907 @default.
• W2087016405 cites W2015492400 @default.
• W2087016405 cites W2021509754 @default.
• W2087016405 cites W2025429873 @default.
• W2087016405 cites W2029482450 @default.
• W2087016405 cites W2032267556 @default.
• W2087016405 cites W2037049045 @default.
• W2087016405 cites W2051075997 @default.
• W2087016405 cites W2054729653 @default.
• W2087016405 cites W2057017828 @default.
• W2087016405 cites W2057042904 @default.
• W2087016405 cites W2062219230 @default.
• W2087016405 cites W2063259146 @default.
• W2087016405 cites W2066944234 @default.
• W2087016405 cites W2077438169 @default.
• W2087016405 cites W2079604897 @default.
• W2087016405 cites W2084678296 @default.
• W2087016405 cites W2146817017 @default.
• W2087016405 cites W2155541999 @default.
• W2087016405 doi "https://doi.org/10.1021/jp0472055" @default.
• W2087016405 hasPublicationYear "2004" @default.
• W2087016405 type Work @default.
• W2087016405 sameAs 2087016405 @default.
• W2087016405 citedByCount "34" @default.
• W2087016405 countsByYear W20870164052012 @default.
• W2087016405 countsByYear W20870164052013 @default.
• W2087016405 countsByYear W20870164052016 @default.
• W2087016405 countsByYear W20870164052017 @default.
• W2087016405 countsByYear W20870164052020 @default.
• W2087016405 countsByYear W20870164052021 @default.
• W2087016405 countsByYear W20870164052023 @default.
• W2087016405 crossrefType "journal-article" @default.
• W2087016405 hasAuthorship W2087016405A5003469584 @default.
• W2087016405 hasAuthorship W2087016405A5042137930 @default.
• W2087016405 hasAuthorship W2087016405A5053704980 @default.
• W2087016405 hasAuthorship W2087016405A5056970547 @default.
• W2087016405 hasAuthorship W2087016405A5076315023 @default.
• W2087016405 hasAuthorship W2087016405A5077734239 @default.
• W2087016405 hasConcept C111429119 @default.
• W2087016405 hasConcept C121332964 @default.
• W2087016405 hasConcept C121530826 @default.
• W2087016405 hasConcept C1276947 @default.
• W2087016405 hasConcept C138716334 @default.
• W2087016405 hasConcept C147789679 @default.
• W2087016405 hasConcept C178790620 @default.
• W2087016405 hasConcept C185592680 @default.
• W2087016405 hasConcept C32909587 @default.
• W2087016405 hasConcept C4839761 @default.
• W2087016405 hasConcept C548442186 @default.
• W2087016405 hasConcept C67787023 @default.
• W2087016405 hasConcept C71240020 @default.
• W2087016405 hasConcept C8010536 @default.
• W2087016405 hasConceptScore W2087016405C111429119 @default.
• W2087016405 hasConceptScore W2087016405C121332964 @default.
• W2087016405 hasConceptScore W2087016405C121530826 @default.
• W2087016405 hasConceptScore W2087016405C1276947 @default.
• W2087016405 hasConceptScore W2087016405C138716334 @default.
• W2087016405 hasConceptScore W2087016405C147789679 @default.
• W2087016405 hasConceptScore W2087016405C178790620 @default.
• W2087016405 hasConceptScore W2087016405C185592680 @default.
• W2087016405 hasConceptScore W2087016405C32909587 @default.
• W2087016405 hasConceptScore W2087016405C4839761 @default.
• W2087016405 hasConceptScore W2087016405C548442186 @default.
• W2087016405 hasConceptScore W2087016405C67787023 @default.
• W2087016405 hasConceptScore W2087016405C71240020 @default.
• W2087016405 hasConceptScore W2087016405C8010536 @default.
• W2087016405 hasIssue "44" @default.
• W2087016405 hasLocation W20870164051 @default.
• W2087016405 hasOpenAccess W2087016405 @default.
• W2087016405 hasPrimaryLocation W20870164051 @default.
• W2087016405 hasRelatedWork W1965613222 @default.
• W2087016405 hasRelatedWork W1984878763 @default.
• W2087016405 hasRelatedWork W2069593487 @default.
• W2087016405 hasRelatedWork W2084257536 @default.
• W2087016405 hasRelatedWork W2087684955 @default.
• W2087016405 hasRelatedWork W2090313096 @default.
• W2087016405 hasRelatedWork W2092581523 @default.
• W2087016405 hasRelatedWork W2121316755 @default.
• W2087016405 hasRelatedWork W4210957245 @default.
• W2087016405 hasRelatedWork W4249784506 @default.
• W2087016405 hasVolume "108" @default.
• W2087016405 isParatext "false" @default.

• next