Matches in SemOpenAlex for { <https://semopenalex.org/work/W2087041604> ?p ?o ?g. }
- W2087041604 endingPage "3954" @default.
- W2087041604 startingPage "3945" @default.
- W2087041604 abstract "Different chiral mono-substituted N-heterocyclic carbene complexes of rhodium were prepared, starting from [Rh(COD)Cl]2 (COD = cyclooctadiene) by addition of free N-heterocyclic carbenes (NHC), or an in-situ deprotonation of the corresponding iminium salt. All new complexes were characterized by spectroscopy methods. In addition, the structures of chloro(η4-1,5-cyclooctadiene)(1,3-di-[(1R,2R,3R,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-3-yl] imidazolin-2-ylidene)rhodium(I) (5a), chloro(η4-1,5-cyclooctadiene)(1,3-di-[(1R,2S,5R)-2-isopropyl-5-menthylcyclohex-1-yl]imidazol-2-ylidene)rhodium(I) (5b) and chloro(η4-1,5-cyclooctadiene)(1,3-di-[(2R,4S,5S)-2-methyl-4-phenyl-1,3-dioxacyclohex-5-yl]imidazolin-2-ylidene)rhodium(I) (5i) were analyzed by DFT-calculations. The enantioselective hydrosilylation of acetophenone, ethylpyruvate and n-propylpyruvate with diphenylsilane and hydrolysis was carried out with chiral C2-symmetrical mono-substituted N-heterocyclic carbene rhodium complexes giving for the first time an enantioselective excess of up to 74% ee in the case of the n-propylpyruvate." @default.
- W2087041604 created "2016-06-24" @default.
- W2087041604 creator A5009678133 @default.
- W2087041604 creator A5028534413 @default.
- W2087041604 creator A5040208014 @default.
- W2087041604 creator A5091636870 @default.
- W2087041604 date "2011-12-01" @default.
- W2087041604 modified "2023-10-18" @default.
- W2087041604 title "Synthesis and characterization of chiral mono N-heterocyclic carbene-substituted rhodium complexes and their catalytic properties in hydrosilylation reactions" @default.
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