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• W2087053742 endingPage "3741" @default.
• W2087053742 startingPage "3741" @default.
• W2087053742 abstract "Excitation of trans-dioxo-osmium(VI) complexes in the solid state and in fluid solutions at room temperature at 350–400 nm results in red emission with maxima at 620–710 nm. Rate constants for electron-transfer quenching of trans-[OsVI(L1)O2]2+*(L1= 1,4,8,11-tetramethyl-1,4,8,11-tetra-azacyclotetradecane) and trans-[OsVI(L4)O2]2+*{L4=meso-2,3,7,11,12-pentamethyl-3,7,11,17-tetra-azabicyclo[11.3.1 ]heptadeca-1 (17),13,15-triene} by a series of structurally related aromatic hydrocarbons with varying redox potentials have been determined in acetonitrile. The 3Eg states of trans-[OsVI(L1)O2]2+ and trans-[OsVI(L4)O2]2+ are powerful one-electron oxidants, the excited-state reduction potentials of which in acetonitrile, E°(OsVI*–OsV), have been found to be 2.39(10) and 2.00(10) V vs. normal hydrogen electrode respectively, which agree well with estimations using spectroscopic and electrochemical data." @default.
• W2087053742 created "2016-06-24" @default.
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• W2087053742 date "1990-01-01" @default.
• W2087053742 modified "2023-10-13" @default.
• W2087053742 title "Electron-transfer chemistry of the luminescent excited state of trans-dioxo-osmium(VI)" @default.
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• W2087053742 doi "https://doi.org/10.1039/dt9900003741" @default.
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