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- W2087081491 abstract "The specific heat capacity of antiferromagnetic CoBr26H2O has been measured in the 1.2-5.0K range using the heat pulse technique. The results indicate an effective spin S'=1/2 system having a lambda transition at TN=3.135+or-0.005K. The authors find that 58+or-2% of the total entropy increase is needed to reach TN compared with 49% for isomorphic CoCl26H2O. Tables of critical values and estimates of the average nearest-neighbour exchange parameters are presented. Within the limitations of an oversimplified model, it is concluded that the thermodynamics of CoBr26H2O and CoCl26H2O agree with three-dimensional Heisenberg model calculations. The best estimate of the average nearest-neighbour exchange constant is -1.6K for the bromide and -1.3K for the chloride. The greater short-range order observed for the chloride is attributed to the effect of the relatively larger intrasublattice coupling." @default.
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- W2087081491 date "1975-04-21" @default.
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- W2087081491 title "Specific heat of CoBr<sub>2</sub>6H<sub>2</sub>O in the 1-5K range" @default.
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- W2087081491 doi "https://doi.org/10.1088/0022-3719/8/8/025" @default.
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