FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2087112255> ?p ?o ?g. }

• W2087112255 endingPage "95" @default.
• W2087112255 startingPage "84" @default.
• W2087112255 abstract "The bis-4-phosphinito ligands [(p-Ph2POC6H4)2X] (X=O, 1; X=CMe2, 2; X=S, 3) react with [Ru(η6-p-cymene)Cl2]2 to form the binuclear complexes {[Ru(η6-p-cymene)Cl2]2[μ-(p-Ph2POC6H4)2X]} (X=O, 4; X=CMe2, 5; X=S, 6) in good yields as red air stable solids. The crystal structures of 4–6 were determined by X-ray analysis. In acetonitrile and in the presence of AgPF6 (1:1 equiv. with respect to Ru), complexes 4–6 undergo substitution to yield the cationic complexes {[Ru(η6-p-cymene)Cl(CH3CN)]2[μ-(p-Ph2POC6H4)2X]}[PF6]2 (X=O, 7; X=CMe2, 8; X=S, 9), whose stability in solution is very limited. The acetonitrile ligand in complexes 7–9 can be easily replaced by carbon monoxide; the products {[Ru(η6-p-cymene)Cl(CO)]2[μ-(p-Ph2POC6H4)2X]}[PF6]2 (X=O, 10; X=CMe2, 11; X=S, 12) can only be detected in solution under a CO atmosphere and have limited stability. The reaction of [Rh(η5-C5Me5)Cl2]2 with ligands 1–3 results in the formation of the complexes {[Rh(η5-C5Me5)Cl2]2[μ-(p-Ph2POC6H4)2X]} (X=O, 13; X=CMe2, 14; X=S, 15), which have been isolated as red–orange air stable solids. The cationic complexes {[Rh(η5-C5Me5)Cl(CH3CN)]2[μ-(p-Ph2POC6H4)2X]}[PF6]2 (X=O, 16; X=CMe2, 17; X=S, 18), in which the metal atoms are stereogenic centers, have been obtained from the corresponding complexes 13–15, by treatment in CH3CN with AgPF6, and have been characterized only in solution by 31P{1H} NMR spectra and conductivity measurements. On reaction with ligands 1–3, [Rh(η5-C5H5)(CO)2] was converted into the binuclear phosphinito-bridged complexes {[Rh(η5-C5H5)(CO)]2[μ-(p-Ph2POC6H4)2X]} (X=O, 19; X=CMe2, 20; X=S, 21). The reactions of the binuclear complex {[Rh(η5-C5H5)(CO)]2[μ-(p-Ph2POC6H4)2S]} (21) with CH3I, S-(+)-1-bromo-2-methylbutane and racemic PhCH(CH3)Br were also studied. The products were the corresponding acyl derivatives. The reaction of 21 with neat CH3I easily afforded the complex {[Rh(η5-C5H5)(COCH3)I]2[μ-(p-Ph2POC6H4)2S]} (23), whose structural determination by X-ray analysis is also reported." @default.
• W2087112255 created "2016-06-24" @default.
• W2087112255 creator A5007294860 @default.
• W2087112255 creator A5013759035 @default.
• W2087112255 creator A5016089358 @default.
• W2087112255 creator A5056932242 @default.
• W2087112255 creator A5082349129 @default.
• W2087112255 date "1999-09-01" @default.
• W2087112255 modified "2023-10-17" @default.
• W2087112255 title "Diphosphinito-bridged ruthenium(II) and rhodium(III) complexes with stereogenic metal centers" @default.
• W2087112255 cites W1968331067 @default.
• W2087112255 cites W1972580956 @default.
• W2087112255 cites W1982007697 @default.
• W2087112255 cites W1982445534 @default.
• W2087112255 cites W1987650820 @default.
• W2087112255 cites W1996853488 @default.
• W2087112255 cites W2008397095 @default.
• W2087112255 cites W2017910827 @default.
• W2087112255 cites W2020262890 @default.
• W2087112255 cites W2041603559 @default.
• W2087112255 cites W2044792680 @default.
• W2087112255 cites W2045399620 @default.
• W2087112255 cites W2045662484 @default.
• W2087112255 cites W2047322882 @default.
• W2087112255 cites W2057295383 @default.
• W2087112255 cites W2062637953 @default.
• W2087112255 cites W2063391250 @default.
• W2087112255 cites W2077503811 @default.
• W2087112255 cites W2077764575 @default.
• W2087112255 cites W2079879677 @default.
• W2087112255 cites W2085517815 @default.
• W2087112255 cites W2091885535 @default.
• W2087112255 cites W2092304568 @default.
• W2087112255 cites W2094413899 @default.
• W2087112255 cites W2094508612 @default.
• W2087112255 cites W2120036061 @default.
• W2087112255 cites W2135999763 @default.
• W2087112255 cites W2153336822 @default.
• W2087112255 cites W2953349320 @default.
• W2087112255 cites W3005496588 @default.
• W2087112255 cites W4232602462 @default.
• W2087112255 doi "https://doi.org/10.1016/s0020-1693(99)00174-7" @default.
• W2087112255 hasPublicationYear "1999" @default.
• W2087112255 type Work @default.
• W2087112255 sameAs 2087112255 @default.
• W2087112255 citedByCount "5" @default.
• W2087112255 countsByYear W20871122552013 @default.
• W2087112255 countsByYear W20871122552020 @default.
• W2087112255 crossrefType "journal-article" @default.
• W2087112255 hasAuthorship W2087112255A5007294860 @default.
• W2087112255 hasAuthorship W2087112255A5013759035 @default.
• W2087112255 hasAuthorship W2087112255A5016089358 @default.
• W2087112255 hasAuthorship W2087112255A5056932242 @default.
• W2087112255 hasAuthorship W2087112255A5082349129 @default.
• W2087112255 hasConcept C115624301 @default.
• W2087112255 hasConcept C116569031 @default.
• W2087112255 hasConcept C134195300 @default.
• W2087112255 hasConcept C146686406 @default.
• W2087112255 hasConcept C155647269 @default.
• W2087112255 hasConcept C161790260 @default.
• W2087112255 hasConcept C170493617 @default.
• W2087112255 hasConcept C178790620 @default.
• W2087112255 hasConcept C183882617 @default.
• W2087112255 hasConcept C185592680 @default.
• W2087112255 hasConcept C2777463227 @default.
• W2087112255 hasConcept C521398313 @default.
• W2087112255 hasConcept C544153396 @default.
• W2087112255 hasConcept C55493867 @default.
• W2087112255 hasConcept C555196967 @default.
• W2087112255 hasConcept C71240020 @default.
• W2087112255 hasConcept C8010536 @default.
• W2087112255 hasConceptScore W2087112255C115624301 @default.
• W2087112255 hasConceptScore W2087112255C116569031 @default.
• W2087112255 hasConceptScore W2087112255C134195300 @default.
• W2087112255 hasConceptScore W2087112255C146686406 @default.
• W2087112255 hasConceptScore W2087112255C155647269 @default.
• W2087112255 hasConceptScore W2087112255C161790260 @default.
• W2087112255 hasConceptScore W2087112255C170493617 @default.
• W2087112255 hasConceptScore W2087112255C178790620 @default.
• W2087112255 hasConceptScore W2087112255C183882617 @default.
• W2087112255 hasConceptScore W2087112255C185592680 @default.
• W2087112255 hasConceptScore W2087112255C2777463227 @default.
• W2087112255 hasConceptScore W2087112255C521398313 @default.
• W2087112255 hasConceptScore W2087112255C544153396 @default.
• W2087112255 hasConceptScore W2087112255C55493867 @default.
• W2087112255 hasConceptScore W2087112255C555196967 @default.
• W2087112255 hasConceptScore W2087112255C71240020 @default.
• W2087112255 hasConceptScore W2087112255C8010536 @default.
• W2087112255 hasIssue "1" @default.
• W2087112255 hasLocation W20871122551 @default.
• W2087112255 hasOpenAccess W2087112255 @default.
• W2087112255 hasPrimaryLocation W20871122551 @default.
• W2087112255 hasRelatedWork W1989657791 @default.
• W2087112255 hasRelatedWork W1999832496 @default.
• W2087112255 hasRelatedWork W2008841073 @default.
• W2087112255 hasRelatedWork W2087112255 @default.
• W2087112255 hasRelatedWork W2112627295 @default.
• W2087112255 hasRelatedWork W2114257229 @default.

• next