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- W2087125775 abstract "Two different levels of the free-volume approximation for describing one-dimensional mixtures of hard rods of two different lengths are analysed and tested against the exact solution. The mean-field level free-volume approach, where only the statistically pre-averaged free volume of the larger rods is accounted for, yields a spurious phase transition. Taking correlations into account not only gives better quantitative results, it also shows qualitative right physics, i.e. no phase transition." @default.
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- W2087125775 date "2002-07-01" @default.
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- W2087125775 title "The importance of correlations in free-volume models for depletion phenomena" @default.
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- W2087125775 doi "https://doi.org/10.1016/s0378-4371(02)00743-4" @default.
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