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• W2087152122 abstract "Bench‐stable complexes of the type [Ir(COD)(NHC)Cl] (NHC = N ‐heterocyclic carbene) have been investigated within the field of hydrogen isotope exchange. By employing a sterically encumbered NHC within such complexes and catalyst loadings of only 5 mol%, moderate to high deuterium incorporations were achieved across a range of aromatic ketones and nitrogen‐based heterocycles. The simple and synthetically accessible catalysts reported herein present alternatives to phosphine‐based species and increase the available labelling systems with respect to established iridium‐based isotope exchange methodologies." @default.
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• W2087152122 date "2013-07-01" @default.
• W2087152122 modified "2023-10-07" @default.
• W2087152122 title "Application of neutral iridium(I)<i>N</i>-heterocyclic carbene complexes in<i>ortho</i>-directed hydrogen isotope exchange" @default.
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• W2087152122 doi "https://doi.org/10.1002/jlcr.3084" @default.
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