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- W2087177225 abstract "Ruthenium dioxide-(RuO2)-containing carbon paste electrodes exhibiting electrocatalytic responses toward alcohols are described. The electrocatalytic behavior is exploited for developing a highly stable and sensitive flow-detection scheme for simple alcohols with a constant-potential operation (+0.4 V vs. Ag/AgCl). The optimization of the system with respect to variables such as pH, flow rate, operating potential, and RuO2–surface “loading” is reported. The electrode response as stable over 2 weeks with a signal loss of 6%. Repeated injections (60) of methanol over a 120 minute period yielded a relative standard deviation of 3.4%. Detection limits for the various alcohols are dependent on the number and position of the hydroxyl groups, with limits ranging from 30 ng for glycerol to 3 μg for ethanol. Use of these electrodes in liquid chromatography with electrochemical detection is envisaged." @default.
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- W2087177225 date "1991-01-01" @default.
- W2087177225 modified "2023-10-06" @default.
- W2087177225 title "Electrocatalysis and flow detection of alcohols at ruthenium dioxide-modified electrodes" @default.
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- W2087177225 doi "https://doi.org/10.1002/elan.1140030107" @default.
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