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- W2087192445 abstract "Abstract An In(III)/Si catalyst system effects the direct allyl substitution of alcohols and silyl ethers under mild conditions. A deoxygenation of alcohols is also promoted by InCl 3 catalyst. This method requires no pretreatment or protection of hydroxy groups or deprotection of siloxy groups. The completion of the catalytic allylation depends on the low oxophilicity and high halophilicity of In(III) halide species, and other representative Lewis acids such as AlCl 3 and BF 3 have no catalytic activity for the allylations. The oxophilicity and halophilicity are also demonstrated by NMR studies." @default.
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- W2087192445 date "2008-01-01" @default.
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- W2087192445 title "Reaction of alcohols and silyl ethers in the presence of an indium/silicon-based catalyst system: Deoxygenation and allyl substitution" @default.
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