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- W2087278839 abstract "Abstract The a.c. impedance of Pt∣NaCl∣Pt and C∣NaCl∣C cells was measured in the frequency range from 10−3 to 103 Hz. Two contributions to the interface impedance could be distinguished, hindered charge transfer and an adsorption/desorption or slow reaction contribution, the latter being the rate determining step in the frequency range studied. An approximately symmetric nonlinear dependence of both the capacitance and the conductance on overvoltage was found at the lowest frequencies, indicating that the crystal/electrode interface is in a state which can be characterized as close to equilibrium. It should be ensured by two electrochemical reactions of approximately equal rates. The concept of a temporarily reversible electrode is introduced. It is a result of the ability of ions to discharge at the interface and to produce a finite reservoir of adsorbed or absorbed reaction products. An external voltage increases or reduces this reservoir, and therefore only a transient electric current may be carried by a backward reaction." @default.
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- W2087278839 date "1983-01-01" @default.
- W2087278839 modified "2023-10-18" @default.
- W2087278839 title "A complex impedance study of Pt∣NaCl and C∣NaCl interfaces" @default.
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- W2087278839 doi "https://doi.org/10.1016/0022-3697(83)90129-4" @default.
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