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• W2087286002 abstract "Three new complexes of group thirteen metals, gallium(III), indium(III), and thallium(III) with proton transfer compounds, obtained from 2,6-pyridinedicarboxylic acid (dipicolinic acid), were synthesized and characterized using elemental analysis, IR, 1H and 13C NMR spectroscopy and single crystal X-ray diffraction. The gallium(III) and indium(III) complexes were prepared using (pydaH2)(pydc) (pyda = 2,6-pyridinediamine, pydcH2 = dipicolinic acid) and thallium(III) complex was obtained from (creatH)(pydcH) (creat = creatinine). The chemical formulae and space groups of the complexes are (pydaH)[Ga(pydc)2] · 3.25H2O · CH3OH, (1), [In(pydc)(pydcH)(H2O)2] · 5H2O, Pna21 (2) and [Tl2(pydcH)3(pydc)(H2O)2], (3). Non-covalent interactions such as ion-pairing, hydrogen bonding and π-π stacking are discussed. The complexation reactions of pyda, pydc, and pyda + pydc with In3+ and Ga3+ ions in aqueous solution were investigated by potentiometric pH titrations, and the equilibrium constants for all major complexes formed are described." @default.
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• W2087286002 date "2006-01-01" @default.
• W2087286002 modified "2023-10-16" @default.
• W2087286002 title "Novel Complexes of Gallium(III), Indium(III), and Thallium(III) with Pyridine-Containing Proton Transfer Ion Pairs Obtained from Dipicolinic Acid - Synthesis, Characterization and X-ray Crystal Structure" @default.
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• W2087286002 doi "https://doi.org/10.1002/zaac.200500321" @default.
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