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- W2087291221 abstract "The ${text{As}}_{2}{text{S}}_{3}$ melt at room pressure represents a liquid having a three-dimensional network structure, semiconducting properties, and a huge viscosity. We have found that under high pressure a considerable change in the medium and short-range structure of this liquid is observed. Intermediate-range order correlations in the atomic arrangement almost disappear under pressure and an increase in the coordination number is observed. This increase is evidently associated with the formation of a significant fraction of the wrong neighbors As-As. At pressures above 6 GPa, the ${text{As}}_{2}{text{S}}_{3}$ melt has a conductivity close to the minimum conductivity value of $ensuremath{sim}100text{ }{text{Ohm}}^{ensuremath{-}1}text{ }{text{cm}}^{ensuremath{-}1}$ and a moderate viscosity of $ensuremath{sim}0.5--1text{ }text{Pa}text{ }text{s}$. Obviously, the transition under high pressures to such ``strange metallic'' liquids are bound to be seen in many other chalcogenide melts with network structure." @default.
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- W2087291221 date "2010-10-20" @default.
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- W2087291221 title "Structural transformation yielding an unusual metallic state in liquid<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mtext>As</mml:mtext></mml:mrow><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mtext>S</mml:mtext><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>under high pressure" @default.
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