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• W2087311504 startingPage "121" @default.
• W2087311504 abstract "Boundary effects can have a profound influence on the electrophoretic behavior of a charged entity, in particular, when the entity is nonspherical and its surface conditions are dependent upon the nearby environment. In this study, the electrophoresis of a spheroid along the axis of an uncharged cylindrical pore is analyzed for the case where the electrical potential is low and the applied electric field is weak. We consider the case where the surface of a particle contains dissociable acidic and basic functional groups, which simulate biological colloids and entities covered by an artificial membrane. This leads to a mixed-type boundary value problem, which extends the conventional constant-surface-potential and constant-surface-charge-density models to a more general case. The effects of the particle aspect ratio, the relative magnitudes of particle and pore, the thickness of the double layer surrounding a particle, and the pH of the liquid phase on the electrophoretic mobility of a particle are investigated. Several interesting results are observed; for example, if the volume of a particle is fixed, its mobility may have a local maximum as the relative magnitudes of its two axes vary." @default.
• W2087311504 created "2016-06-24" @default.
• W2087311504 creator A5004378787 @default.
• W2087311504 creator A5086764828 @default.
• W2087311504 date "2003-08-01" @default.
• W2087311504 modified "2023-10-17" @default.
• W2087311504 title "Electrophoresis of a charge-regulated spheroid along the axis of an uncharged cylindrical pore" @default.
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• W2087311504 doi "https://doi.org/10.1016/s0021-9797(03)00331-x" @default.
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• W2087311504 hasPublicationYear "2003" @default.
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