FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2087331359> ?p ?o ?g. }

• W2087331359 endingPage "197" @default.
• W2087331359 startingPage "189" @default.
• W2087331359 abstract "Abstract The reduction of iodate on a dropping mercury electrode was studied over a wide range of temperatures, and compared with earlier studies on the reduction of bromate under nearly identical conditions. A fully computerized experimental setup was used. This allows collection of a large number of experimental points, for proper statistical analysis of the data. The transfer coefficient was found to be a function of temperature, decreasing by about 10% with increasing temperature over 80°C. This behavior is very different from that found earlier for the reduction of bromate, where α is strictly independent of temperature. The reduction of iodate occurs at less negative potentials than that of bromate, far from interference by solvent decomposition. This allows very accurate determination of the Tafel parameters, but makes diffuse double layer correction more difficult, since specific adsorption cannot be excluded. We have tested the effect of specific adsorption of I − by changing the concentration of iodate and by adding as much as 10 mM of NaI. The effect of the chloride was tested by replacing it with fluoride as the anion of the supporting electrolyte. The effect of surface active agents was tested by adding Triton X-100. Small variations in the transfer coefficients were observed between these experiments, but the temperature dependence of α persisted in all cases. Correction for the diffuse double layer effect changes the value of the transfer coefficient, but does not eliminate its temperature dependence. It must be concluded that the transfer coefficient for the reduction of iodate is temperature dependent, and this dependence cannot be attributed to experimental inaccuracy or inadequate correction for the effect of the diffuse double layer resulting from specific adsorption. This is in contrast to our findings for the reduction of bromate, hydroxylamine and the H 3 O + ion, for all of which α is found to be strictly independent of temperature." @default.
• W2087331359 created "2016-06-24" @default.
• W2087331359 creator A5000422749 @default.
• W2087331359 creator A5020008665 @default.
• W2087331359 creator A5021199353 @default.
• W2087331359 creator A5089000128 @default.
• W2087331359 date "1996-07-01" @default.
• W2087331359 modified "2023-10-16" @default.
• W2087331359 title "Temperature dependence of the transfer coefficient. The reduction of iodate in alkaline media" @default.
• W2087331359 cites W1966413310 @default.
• W2087331359 cites W1967773546 @default.
• W2087331359 cites W1991843133 @default.
• W2087331359 cites W2025635375 @default.
• W2087331359 cites W2027394162 @default.
• W2087331359 cites W2034205661 @default.
• W2087331359 cites W2035108767 @default.
• W2087331359 cites W2041885929 @default.
• W2087331359 cites W2059721333 @default.
• W2087331359 cites W2061921952 @default.
• W2087331359 cites W2069188289 @default.
• W2087331359 cites W2076831669 @default.
• W2087331359 cites W2086883642 @default.
• W2087331359 cites W2164107687 @default.
• W2087331359 doi "https://doi.org/10.1016/0022-0728(96)04542-1" @default.
• W2087331359 hasPublicationYear "1996" @default.
• W2087331359 type Work @default.
• W2087331359 sameAs 2087331359 @default.
• W2087331359 citedByCount "17" @default.
• W2087331359 countsByYear W20873313592014 @default.
• W2087331359 countsByYear W20873313592015 @default.
• W2087331359 countsByYear W20873313592017 @default.
• W2087331359 crossrefType "journal-article" @default.
• W2087331359 hasAuthorship W2087331359A5000422749 @default.
• W2087331359 hasAuthorship W2087331359A5020008665 @default.
• W2087331359 hasAuthorship W2087331359A5021199353 @default.
• W2087331359 hasAuthorship W2087331359A5089000128 @default.
• W2087331359 hasConcept C111335779 @default.
• W2087331359 hasConcept C179104552 @default.
• W2087331359 hasConcept C185592680 @default.
• W2087331359 hasConcept C2524010 @default.
• W2087331359 hasConcept C2778870691 @default.
• W2087331359 hasConcept C2780284529 @default.
• W2087331359 hasConcept C33923547 @default.
• W2087331359 hasConceptScore W2087331359C111335779 @default.
• W2087331359 hasConceptScore W2087331359C179104552 @default.
• W2087331359 hasConceptScore W2087331359C185592680 @default.
• W2087331359 hasConceptScore W2087331359C2524010 @default.
• W2087331359 hasConceptScore W2087331359C2778870691 @default.
• W2087331359 hasConceptScore W2087331359C2780284529 @default.
• W2087331359 hasConceptScore W2087331359C33923547 @default.
• W2087331359 hasIssue "2" @default.
• W2087331359 hasLocation W20873313591 @default.
• W2087331359 hasOpenAccess W2087331359 @default.
• W2087331359 hasPrimaryLocation W20873313591 @default.
• W2087331359 hasRelatedWork W1992168253 @default.
• W2087331359 hasRelatedWork W2000159270 @default.
• W2087331359 hasRelatedWork W2028729100 @default.
• W2087331359 hasRelatedWork W2063830252 @default.
• W2087331359 hasRelatedWork W2065631585 @default.
• W2087331359 hasRelatedWork W2069929349 @default.
• W2087331359 hasRelatedWork W2089214254 @default.
• W2087331359 hasRelatedWork W2146899465 @default.
• W2087331359 hasRelatedWork W2168062436 @default.
• W2087331359 hasRelatedWork W2952911285 @default.
• W2087331359 hasVolume "410" @default.
• W2087331359 isParatext "false" @default.
• W2087331359 isRetracted "false" @default.
• W2087331359 magId "2087331359" @default.
• W2087331359 workType "article" @default.