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- W2087331391 abstract "For the first time, experimental measurements confirm the real additivity of the currents with micropore arrays, independently of the geometry (square, circular or in crosswise), from one single micropore until 256 micropores, in the case of the assisted transfer of cadmium ions by 8-hydroxyquinolinol (8-HQ). This result was obtained for measurements made by cyclic voltammetry at high concentration of cadmium ions (10−4 M). At lower concentrations (until 10−6 M), measurements performed by square wave voltammetry confirm also this additivity until 64 micropores. A calibration curve performed with a 64 micropores array allows us, in very simple conditions, the quantification of cadmium ions until 11 ppb (100 nM), which is lower than to the imposed limit for this specie in various fields, and in industrial effluents, in particular. The gain of sensitivity is close to 170 compared to measurements performed with one single micropore, illustrating the real interest of these arrays." @default.
- W2087331391 created "2016-06-24" @default.
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- W2087331391 date "2014-02-01" @default.
- W2087331391 modified "2023-09-27" @default.
- W2087331391 title "Perfect additivity of microinterface arrays for liquid-liquid measurements: Application to cadmium ions quantification" @default.
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- W2087331391 doi "https://doi.org/10.1016/j.electacta.2013.12.034" @default.
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