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- W2087331838 abstract "Despite its instability in acidic aqueous solution, acidified Mn(VI) is capable of oxidizing some alcohols and aldehydes. The product composition of the manganese species depends on the nature and the concentration of the substrate and seems to be governed by the relative rates of disproportionation and oxidation reactions involving both Mn(VI) and Mn(V). The high reactivity of Mn(V) and Mn(VI) towards OH-containing substrates indicates the existence of alternative routes to the long-sought hypomanganate and manganate esters which have played a central role as hypothetical intermediates in oxidations by permanganate ion." @default.
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- W2087331838 date "1995-09-01" @default.
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- W2087331838 title "Oxidations with unstable manganese (VI) in acidic solution" @default.
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- W2087331838 doi "https://doi.org/10.1016/0020-1693(95)04656-t" @default.
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