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- W2087346052 abstract "The equilibrium acidities of 14 aldoximes, 4 amidoximes, and 19 ketoximes have been measured in DMSO solution. Homolytic bond dissociation energies (BDEs) for the O-H bonds in these oximes have been estimated by combining the pK HA values thus obtained with the oxidation potentials of their conjugate bdases. The acidities of the corresponding radical cations (pK HA+ I.) were estimated for 32 of these oximes in DMSO as for phenols. The pK HA values for syn-benzaldoxime and acetaldoxime were found to be 20.2 abd 28.5, respectively" @default.
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- W2087346052 date "1992-05-01" @default.
- W2087346052 modified "2023-10-16" @default.
- W2087346052 title "Equilibrium acidities and homolytic bond dissociation energies of the H-O bonds in oximes and amidoximes" @default.
- W2087346052 doi "https://doi.org/10.1021/jo00037a014" @default.
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