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- W2087367698 abstract "Ru(NO)2L2 (L = PPh3) is oxidized in acetonitrile at a Pt electrode in an irreversible two electron process. The main cause for the activation energy is presumably linked to the slow configuration change from a pseudo-tetrahedral to a planar structure. The latter easily releases two electrons giving a dication which can be reversibly reduced to a monocation, as seen in experiments at low temperature. This dication undergoes homogeneous decomposition via a bimolecular reaction with Ru(NO)2L2. In the presence of Cl− it gives a stable product (presumably RuCl2(NO)2L2) which can electrochemically regenerate Ru(NO)2L2." @default.
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- W2087367698 title "Electrochemical oxidation of Ru(NO)2(PPh3)2: an irreversible two electron process" @default.
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- W2087367698 doi "https://doi.org/10.1016/s0020-1693(00)82787-5" @default.
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