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- W2087389181 abstract "Abstract Anodic potentiodynamic polarization curves in 0.1 N H 2 SO 4 and 1 N H 2 SO 4 at 30°C were obtained for amorphous alloys having the following atomic compositions: Fe 83− x Cr x Si 5 B 12 with x = 4.1, 6.2 and 8.3 at.%, and Fe 62.5− y Ni 17.5 Cr y Si 9 B 11 with y = 2.1, 2.5 and 9.4 at.%. An increase in the chromium content increased the corrosion resistance of these alloys. Since X-ray scattering intensity studies on the quenched alloy samples showed no significant effect of chromium concentration on the structure functions, it is concluded that the composition and not the amorphous structure is the important criterion with respect to corrosion properties. The surface morphology of each amorphous alloy, which was polarized for 1 h in 0.1 N H 2 SO 4 at a fixed potential in the passive or transpassive region, was studied using scanning electron microscopy. Pitting was found at transpassive potentials in all the alloys and was promoted by the rough surface present in the as-quenched amorphous ribbons. Auger analysis of the Fe 53.1 Ni 17.5 Cr 9.4 Si 9 B 11 amorphous alloy indicated boron segregation near the surface of the as-quenched alloy and chromium depletion in the transpassive film." @default.
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- W2087389181 date "1984-12-01" @default.
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- W2087389181 title "Corrosion of FeCrSiB and FeCrNiB metallic glasses containing various chromium concentrations" @default.
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- W2087389181 doi "https://doi.org/10.1016/0025-5416(84)90251-9" @default.
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