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• W2087389629 abstract "Mg-based materials are promising candidates for high capacity hydrogen storage. However, their poor hydrogenation/dehydrogenation kinetics and high desorption temperature are the main obstacles to their applications. This paper reports a method for in situ formation of cycle stable CeH2.73-MgH2-Ni nanocomposites, from the hydrogenation of as-melt Mg80Ce18Ni2 alloy, with excellent hydrogen storage performance. The nanocomposites demonstrate reversible hydrogen storage capacity of more than 4.0 wt %, at a low desorption temperature with fast kinetics and long cycle life. The temperature for the full hydrogenation/dehydrogenation cycle of the composites is significantly decreased to 505 K, which is about 100 K lower than that for pure Mg. The hydrogen desorption activation energy is 63 ± 3 kJ/mol H2 for the composites, which is significantly lower than those of Mg3Ce alloy and pure Mg (104 ± 7 and 158 ± 2 kJ/mol H2, respectively). X-ray diffraction and transmission electron microscopy have been used to reveal the mechanism that delivers this excellent cycle stability and fast hydriding/dehydriding kinetics. It is found that the hydriding/dehydriding process is catalyzed by the combination of in situ formed extremely fine CeH2/CeH2.73 and Ni to Mg/MgH2. In addition, this nanocomposite structure can effectively suppress Mg/MgH2 grain growth and enable the material to maintain its high performance for more than 500 hydrogenation dehydrogenation cycles." @default.
• W2087389629 created "2016-06-24" @default.
• W2087389629 creator A5013272472 @default.
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• W2087389629 date "2014-04-08" @default.
• W2087389629 modified "2023-10-17" @default.
• W2087389629 title "Enhanced Hydrogen Storage Kinetics and Stability by Synergistic Effects of <i>in Situ</i> Formed CeH_2.73 and Ni in CeH_2.73-MgH₂-Ni Nanocomposites" @default.
• W2087389629 cites W1964013637 @default.
• W2087389629 cites W1969291610 @default.
• W2087389629 cites W1972495184 @default.
• W2087389629 cites W1973635414 @default.
• W2087389629 cites W1974122841 @default.
• W2087389629 cites W1975046916 @default.
• W2087389629 cites W1975151846 @default.
• W2087389629 cites W1976428733 @default.
• W2087389629 cites W1980408819 @default.
• W2087389629 cites W1980938417 @default.
• W2087389629 cites W1981365879 @default.
• W2087389629 cites W1985650817 @default.
• W2087389629 cites W1997726286 @default.
• W2087389629 cites W1998208668 @default.
• W2087389629 cites W2000368435 @default.
• W2087389629 cites W2002516759 @default.
• W2087389629 cites W2006546243 @default.
• W2087389629 cites W2009275499 @default.
• W2087389629 cites W2013117015 @default.
• W2087389629 cites W2014014285 @default.
• W2087389629 cites W2016632908 @default.
• W2087389629 cites W2019109962 @default.
• W2087389629 cites W2024235130 @default.
• W2087389629 cites W2024422446 @default.
• W2087389629 cites W2026944835 @default.
• W2087389629 cites W2030421764 @default.
• W2087389629 cites W2030966128 @default.
• W2087389629 cites W2032079990 @default.
• W2087389629 cites W2033278935 @default.
• W2087389629 cites W2033644614 @default.
• W2087389629 cites W2041870272 @default.
• W2087389629 cites W2050374750 @default.
• W2087389629 cites W2053856824 @default.
• W2087389629 cites W2054174377 @default.
• W2087389629 cites W2056805753 @default.
• W2087389629 cites W2058717344 @default.
• W2087389629 cites W2059455062 @default.
• W2087389629 cites W2059814992 @default.
• W2087389629 cites W2062630944 @default.
• W2087389629 cites W2063000327 @default.
• W2087389629 cites W2063498130 @default.
• W2087389629 cites W2064172452 @default.
• W2087389629 cites W2065043196 @default.
• W2087389629 cites W2065268698 @default.
• W2087389629 cites W2069003934 @default.
• W2087389629 cites W2069723697 @default.
• W2087389629 cites W2077966704 @default.
• W2087389629 cites W2078764297 @default.
• W2087389629 cites W2080440865 @default.
• W2087389629 cites W2081908437 @default.
• W2087389629 cites W2082303913 @default.
• W2087389629 cites W2082686277 @default.
• W2087389629 cites W2085419173 @default.
• W2087389629 cites W2086988179 @default.
• W2087389629 cites W2087356778 @default.
• W2087389629 cites W2089814664 @default.
• W2087389629 cites W2091620576 @default.
• W2087389629 cites W2091766125 @default.
• W2087389629 cites W2092956353 @default.
• W2087389629 cites W2131153886 @default.
• W2087389629 cites W2152278535 @default.
• W2087389629 cites W2160891362 @default.
• W2087389629 cites W2167383445 @default.
• W2087389629 cites W2167906491 @default.
• W2087389629 cites W2314462548 @default.
• W2087389629 cites W2335153059 @default.
• W2087389629 cites W2950980503 @default.
• W2087389629 doi "https://doi.org/10.1021/jp500439n" @default.
• W2087389629 hasPublicationYear "2014" @default.
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