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- W2087399905 abstract "Abstract Vapour—liquid equilibrium constants at infinite dilution of 1-chloroalkane, 1-bromoalkane and 1-iodoalkane solutes in n-octacosane, n-dotriacontane and n-hexatriacontane solvents were determined by gas—liquid chromatography at five temperatures, 78.0, 84.0, 90.0, 96.0 and 96.0 and 102.0°C. From these constants, the entropy of solution is discussed on the basis of a linear relationship between the number of CH2, CH3, Cl, Br and I groups in the solute molecule and the nature of the solvent molecules. It could be related to the structures of the solute and solvent molecules." @default.
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- W2087399905 date "1984-01-01" @default.
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- W2087399905 title "Entropy of solution at infinite dilution of 1-halogenoalkanes in n-alkane solvents determined by gas—liquid chromatography" @default.
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- W2087399905 doi "https://doi.org/10.1016/s0021-9673(01)87640-8" @default.
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