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- W2087400904 abstract "Time-dependent density functional theory (TD-DFT) calculations using the B3LYP hybrid functional were performed to predict transparencies of alicyclic and heterocyclic compounds in the vacuum ultraviolet (VUV) region. Model compounds of conventional and novel polymer platforms for F2 lithography (157 nm) are devoted for calculations, and the calculated spectra demonstrate very low absorbance of highly fluorinated alicyclic and heterocyclic compounds and also show the effectiveness of introduction of -F and -CF3 groups in reducing the optical absorption at the wavelength. In particular, devised fluorination, such as -CF3 in close proximity of light-absorbing ester functionality, can significantly reduce the absorption of polymer platforms containing norbornane, γ-lactone, and δ-lactone strcutures." @default.
- W2087400904 created "2016-06-24" @default.
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- W2087400904 date "2003-01-01" @default.
- W2087400904 modified "2023-09-26" @default.
- W2087400904 title "DFT Calculations of Photoabsorption Spectra for Alicyclic and Heterocyclic Compounds in the VUV Region" @default.
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- W2087400904 doi "https://doi.org/10.2494/photopolymer.16.537" @default.
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