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- W2087462022 abstract "The chemical compatibility of Ba0.5Sr0.5Co0.8Fe0.2O3-δ (BSCF) electrodes with ceria based electrolytes is investigated under solid oxide fuel cell (SOFC) operation conditions. BSCF reacts with both Ce0.9Gd0.1O1.95 (GDC) and Ce0.8Sm0.2O1.95 (SDC) at 900°C, forming barium cerate (BaxCe1-yMyO3, where M = Gd or Sm). Under cathodic current passage, the interaction between BSCF and ceria-based electrolyte takes place at temperatures as low as 700°C, forming Ba-containing particles (probably barium cerate) at the electrode/electrolyte interface. The results show that cathodic polarization promotes the chemical reaction between BSCF and ceria-based electrolyte. The accelerated reaction between BSCF and ceria is most likely related to the Ba segregation under influence of polarization and/or temperature." @default.
- W2087462022 created "2016-06-24" @default.
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- W2087462022 date "2012-01-01" @default.
- W2087462022 modified "2023-09-27" @default.
- W2087462022 title "Polarization Promoted Chemical Reaction between Ba<sub>0.5</sub>Sr<sub>0.5</sub>Co<sub>0.8</sub>Fe<sub>0.2</sub>O<sub>3-δ</sub>Cathode and Ceria Based Electrolytes of Solid Oxide Fuel Cells" @default.
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- W2087462022 doi "https://doi.org/10.1149/2.026212jes" @default.
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