FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2087463235> ?p ?o ?g. }

• W2087463235 endingPage "32" @default.
• W2087463235 startingPage "9" @default.
• W2087463235 abstract "Molecular orbital calculations at the MNDO level with AM1 or PM3 parametrization give reliable activation enthalpies for chloroalkane and chloroalkene dehydrochlorination. Dehydrochlorination of chloroalkanes and some allyl chlorides is a molecular 1,2-elimination through a four center transition state generated in a synperiplanar conformation. The transition state for chloroalkanes requires very strong polarization of the carbon-chlorine bond. When structure allows, allyl chlorides eliminate hydrogen chloride in a 1,4 process through a six center transition state generated from a cis-configuration of the double bond. This transition state requires much lower activation enthalpy and less polarization of the molecule than does the 1,2 process. Initiation of PVC degradation by 1,2-elimination from normal chain residues, or at the very beginning of degradation from structural irregularities such as tertiary chlorine atoms, takes place through a four center transition state. Allylic chlorine atoms formed in this way or pre-existing in small amounts as structural irregularities have a reactivity not much different from the secondary chlorine atoms of the main chain of the polymer if they adopt a trans- configuration of the double bond. On the other hand, if allylic chlorine atoms have a cis- configuration, they rapidly eliminate hydrogen chloride, forming conjugated polyenes through a transition state of six centers. This elimination constitutes the chain reactions in the PVC degradation process. The chain stops when a relatively stable trans- conformation of the allylic chloride is formed." @default.
• W2087463235 created "2016-06-24" @default.
• W2087463235 creator A5068961269 @default.
• W2087463235 creator A5072865244 @default.
• W2087463235 date "1995-01-01" @default.
• W2087463235 modified "2023-09-28" @default.
• W2087463235 title "Degradation and stabilization of poly (vinyl chloride). IV. Molecular orbital calculations of activation enthalpies for dehydrochlorination of chloroalkanes and chloroalkenes" @default.
• W2087463235 cites W1245355896 @default.
• W2087463235 cites W1562490899 @default.
• W2087463235 cites W1572097823 @default.
• W2087463235 cites W1592310518 @default.
• W2087463235 cites W1912100387 @default.
• W2087463235 cites W1969039562 @default.
• W2087463235 cites W1972481090 @default.
• W2087463235 cites W1976106600 @default.
• W2087463235 cites W1980516143 @default.
• W2087463235 cites W1986192195 @default.
• W2087463235 cites W1986451777 @default.
• W2087463235 cites W1990276182 @default.
• W2087463235 cites W1995003847 @default.
• W2087463235 cites W1995993674 @default.
• W2087463235 cites W1998189055 @default.
• W2087463235 cites W1999237949 @default.
• W2087463235 cites W2005134393 @default.
• W2087463235 cites W2005474097 @default.
• W2087463235 cites W2006930438 @default.
• W2087463235 cites W2008990936 @default.
• W2087463235 cites W2012457343 @default.
• W2087463235 cites W2012880883 @default.
• W2087463235 cites W2020799196 @default.
• W2087463235 cites W2022352326 @default.
• W2087463235 cites W2022673131 @default.
• W2087463235 cites W2024531389 @default.
• W2087463235 cites W2024791964 @default.
• W2087463235 cites W2028730508 @default.
• W2087463235 cites W2035816380 @default.
• W2087463235 cites W2037019860 @default.
• W2087463235 cites W2039275050 @default.
• W2087463235 cites W2041085089 @default.
• W2087463235 cites W2045968198 @default.
• W2087463235 cites W2048671619 @default.
• W2087463235 cites W2053862526 @default.
• W2087463235 cites W2057647035 @default.
• W2087463235 cites W2057688485 @default.
• W2087463235 cites W2062999897 @default.
• W2087463235 cites W2064928152 @default.
• W2087463235 cites W2066263735 @default.
• W2087463235 cites W2067640711 @default.
• W2087463235 cites W2067944688 @default.
• W2087463235 cites W2069390395 @default.
• W2087463235 cites W2070010056 @default.
• W2087463235 cites W2070326148 @default.
• W2087463235 cites W2073246783 @default.
• W2087463235 cites W2076772313 @default.
• W2087463235 cites W2077973224 @default.
• W2087463235 cites W2079100325 @default.
• W2087463235 cites W2085266717 @default.
• W2087463235 cites W2105575337 @default.
• W2087463235 cites W2121408693 @default.
• W2087463235 cites W2123563654 @default.
• W2087463235 cites W2125154025 @default.
• W2087463235 cites W2126475695 @default.
• W2087463235 cites W2127336290 @default.
• W2087463235 cites W2142431441 @default.
• W2087463235 cites W2155358697 @default.
• W2087463235 cites W2158354288 @default.
• W2087463235 cites W2158752948 @default.
• W2087463235 cites W2313670576 @default.
• W2087463235 cites W2314255302 @default.
• W2087463235 cites W2316374330 @default.
• W2087463235 cites W2318694620 @default.
• W2087463235 cites W2319896462 @default.
• W2087463235 cites W2324042243 @default.
• W2087463235 cites W2329391647 @default.
• W2087463235 cites W2333853073 @default.
• W2087463235 cites W2949559534 @default.
• W2087463235 cites W2949713904 @default.
• W2087463235 cites W2950903013 @default.
• W2087463235 cites W2951395612 @default.
• W2087463235 cites W3004524371 @default.
• W2087463235 cites W3004773996 @default.
• W2087463235 doi "https://doi.org/10.1016/0141-3910(94)00085-m" @default.
• W2087463235 hasPublicationYear "1995" @default.
• W2087463235 type Work @default.
• W2087463235 sameAs 2087463235 @default.
• W2087463235 citedByCount "19" @default.
• W2087463235 countsByYear W20874632352012 @default.
• W2087463235 countsByYear W20874632352014 @default.
• W2087463235 countsByYear W20874632352015 @default.
• W2087463235 crossrefType "journal-article" @default.
• W2087463235 hasAuthorship W2087463235A5068961269 @default.
• W2087463235 hasAuthorship W2087463235A5072865244 @default.
• W2087463235 hasConcept C120095180 @default.
• W2087463235 hasConcept C121332964 @default.
• W2087463235 hasConcept C155647269 @default.
• W2087463235 hasConcept C15920480 @default.
• W2087463235 hasConcept C161790260 @default.
• W2087463235 hasConcept C178790620 @default.

• next