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- W2087484539 abstract "Abstract The novel tricyclic polychalcogenide anions [Sb 2 Se 12 ] 2– and [Te 12 ] 4– were obtained by reduction of elemental selenium and tellurium with Li 3 Sb and subsequent crystallization with the crown ether 12‐crown‐4 in ethylenediamine. According to single‐crystal structure analysis, [Li(12‐crown‐4) 2 ] 2 [Sb 2 Se 12 ] consists of two six‐membered (Se 5 Sb)‐rings that are connected via a central (Sb 2 Se 2 )‐ring. [Li(12‐crown‐4) 2 ] 4 [Te 12 ](12‐crown‐4) 2 contains the tricyclic [Te 12 ] 4– anion, consisting of two four‐membered tellurium rings and a central Te 8 ‐ring. EDX analysis proves that the latter compound does not contain antimony." @default.
- W2087484539 created "2016-06-24" @default.
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- W2087484539 date "2009-10-01" @default.
- W2087484539 modified "2023-10-17" @default.
- W2087484539 title "Two Tricyclic Polychalcogenides in [Li(12-crown-4)<sub>2</sub>]<sub>2</sub>[Sb<sub>2</sub>Se<sub>12</sub>] and [Li(12-crown-4)<sub>2</sub>]<sub>4</sub>[Te<sub>12</sub>]·(12-crown-4)<sub>2</sub>" @default.
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- W2087484539 doi "https://doi.org/10.1002/zaac.200900178" @default.
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