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• W2087486228 abstract "Electron paramagnetic resonance (EPR) spectra of Ce 3+ in LiLuF 4 (LLF) and LiSr 0.8 Ca 0.2 AlF 6 (LSCAF) observed at low temperatures (<20 v K) show that the Ce 3+ centers have tetragonal and pseudo-trigonal symmetry with ( g  , g “ )=(2.751, 1.467) and (2.14, 0.80), respectively. The EPR lines of Ce 3+ in LSCAF are inhomogeneously broadened by different Ce 3+ configurations which correspond to the random occupation of the second nearest neighbor cation sites by Ca 2+ and Sr 2+ and/or charge compensators. These EPR results indicate that the Ce 3+ centers in LLF and LSCAF are associated with substitution of Ce 3+ for Lu 3+ with eight-fold coordination and Sr 2+ /Ca 2+ with six-fold coordination, respectively. Fourier transform infrared absorption has been used to measure transitions between the 2 F 5/2 ground state and the 2 F 7/2 multiplet of Ce 3+ in LLF at 10 v K. The optical absorption and luminescence of Ce 3+ :LLF and Ce 3+ :LSCAF in the UV range are strongly polarized. The energy levels and polari..." @default.
• W2087486228 created "2016-06-24" @default.
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• W2087486228 date "2002-01-01" @default.
• W2087486228 modified "2023-09-27" @default.
• W2087486228 title "Site symmetry and crystal field splittings of Ce 3+ in LiLuF 4 and LiSr 0.8 Ca 0.2 AlF 6" @default.
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• W2087486228 doi "https://doi.org/10.1080/10420150215760" @default.
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