FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2087505414> ?p ?o ?g. }

• W2087505414 endingPage "3980" @default.
• W2087505414 startingPage "3976" @default.
• W2087505414 abstract "The reaction of 6,6-dimethylfulvene with M(CH2Ph)4 (M = Zr, Hf) in benzene gives [η5-C5H4(CMe2CH2Ph)]M(CH2Ph)3 (1, M = Zr; 2, M = Hf) without any observable byproducts. A similar reaction for M = Ti is not observed. The single-crystal X-ray study of 1 shows a three-legged piano-stool geometry with an η2-bound benzyl ligand. A second equivalent of 6,6-dimethylfulvene does not react with either 1 or 2. The bulkier 6,6-diphenyfulvene only reacts cleanly with the more Lewis acidic Hf(CH2Ph)4 to give [η5-C5H4(CPh2CH2Ph)]Hf(CH2Ph)3 (3). Using the tetraamido complexes M(NMe2)4 and 6,6-dimethylfulvene, one obtains dimethylamine and [η5-C5H4(CMeCH2)]M(NMe2)3 (4 for M = Zr) in good yield. These products are formally derived from the deprotonation of a fulvene methyl group and subsequent coordination of the resulting 2-propenylcyclopentadienyl fragment. Reaction of 4 and 6,6-dimethylfulvene affords the bent metallocene [η5-C5H4(CMeCH2)]2Zr(NMe2)2 (5). Excess 8,8-dimethylbenzofulvene and M(NMe2)4 provides exclusively the product with only one coordinated indene." @default.
• W2087505414 created "2016-06-24" @default.
• W2087505414 creator A5020725876 @default.
• W2087505414 creator A5040619183 @default.
• W2087505414 creator A5051743081 @default.
• W2087505414 date "1999-08-28" @default.
• W2087505414 modified "2023-09-27" @default.
• W2087505414 title "Fulvene to Cyclopentadienyl Conversion with Homoleptic Complexes of Zirconium and Hafnium" @default.
• W2087505414 cites W1972929500 @default.
• W2087505414 cites W1979914488 @default.
• W2087505414 cites W1990537448 @default.
• W2087505414 cites W1991372092 @default.
• W2087505414 cites W1991834651 @default.
• W2087505414 cites W1993805710 @default.
• W2087505414 cites W1997756225 @default.
• W2087505414 cites W1998824780 @default.
• W2087505414 cites W2000728555 @default.
• W2087505414 cites W2007953865 @default.
• W2087505414 cites W2011253595 @default.
• W2087505414 cites W2017918361 @default.
• W2087505414 cites W2026568630 @default.
• W2087505414 cites W2027468764 @default.
• W2087505414 cites W2032113863 @default.
• W2087505414 cites W2032242048 @default.
• W2087505414 cites W2040553952 @default.
• W2087505414 cites W2061720805 @default.
• W2087505414 cites W2064325329 @default.
• W2087505414 cites W2065668067 @default.
• W2087505414 cites W2073150497 @default.
• W2087505414 cites W2074198098 @default.
• W2087505414 cites W2079859547 @default.
• W2087505414 cites W2081360490 @default.
• W2087505414 cites W2081584642 @default.
• W2087505414 cites W2144332006 @default.
• W2087505414 cites W2153016371 @default.
• W2087505414 cites W2153900045 @default.
• W2087505414 cites W2313721876 @default.
• W2087505414 cites W2324222434 @default.
• W2087505414 cites W2949410973 @default.
• W2087505414 cites W2949593745 @default.
• W2087505414 cites W2949844445 @default.
• W2087505414 cites W2951016404 @default.
• W2087505414 cites W2951308400 @default.
• W2087505414 cites W2952318465 @default.
• W2087505414 cites W4251806080 @default.
• W2087505414 doi "https://doi.org/10.1021/om990402j" @default.
• W2087505414 hasPublicationYear "1999" @default.
• W2087505414 type Work @default.
• W2087505414 sameAs 2087505414 @default.
• W2087505414 citedByCount "23" @default.
• W2087505414 countsByYear W20875054142013 @default.
• W2087505414 countsByYear W20875054142014 @default.
• W2087505414 countsByYear W20875054142015 @default.
• W2087505414 countsByYear W20875054142016 @default.
• W2087505414 countsByYear W20875054142017 @default.
• W2087505414 countsByYear W20875054142020 @default.
• W2087505414 countsByYear W20875054142023 @default.
• W2087505414 crossrefType "journal-article" @default.
• W2087505414 hasAuthorship W2087505414A5020725876 @default.
• W2087505414 hasAuthorship W2087505414A5040619183 @default.
• W2087505414 hasAuthorship W2087505414A5051743081 @default.
• W2087505414 hasConcept C115624301 @default.
• W2087505414 hasConcept C116569031 @default.
• W2087505414 hasConcept C118629725 @default.
• W2087505414 hasConcept C120665830 @default.
• W2087505414 hasConcept C121332964 @default.
• W2087505414 hasConcept C134121241 @default.
• W2087505414 hasConcept C135361552 @default.
• W2087505414 hasConcept C145148216 @default.
• W2087505414 hasConcept C155647269 @default.
• W2087505414 hasConcept C161790260 @default.
• W2087505414 hasConcept C163638829 @default.
• W2087505414 hasConcept C170493617 @default.
• W2087505414 hasConcept C178790620 @default.
• W2087505414 hasConcept C179104552 @default.
• W2087505414 hasConcept C181458950 @default.
• W2087505414 hasConcept C185592680 @default.
• W2087505414 hasConcept C191897082 @default.
• W2087505414 hasConcept C192562407 @default.
• W2087505414 hasConcept C207114421 @default.
• W2087505414 hasConcept C2776396359 @default.
• W2087505414 hasConcept C2778981380 @default.
• W2087505414 hasConcept C2781083472 @default.
• W2087505414 hasConcept C50515024 @default.
• W2087505414 hasConcept C534791751 @default.
• W2087505414 hasConcept C544153396 @default.
• W2087505414 hasConcept C546638069 @default.
• W2087505414 hasConcept C55493867 @default.
• W2087505414 hasConcept C61276311 @default.
• W2087505414 hasConcept C71240020 @default.
• W2087505414 hasConcept C8010536 @default.
• W2087505414 hasConceptScore W2087505414C115624301 @default.
• W2087505414 hasConceptScore W2087505414C116569031 @default.
• W2087505414 hasConceptScore W2087505414C118629725 @default.
• W2087505414 hasConceptScore W2087505414C120665830 @default.
• W2087505414 hasConceptScore W2087505414C121332964 @default.
• W2087505414 hasConceptScore W2087505414C134121241 @default.
• W2087505414 hasConceptScore W2087505414C135361552 @default.

• next