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- W2087514910 abstract "Nitridotris(neopentyl)molybdenum(VI) and its oxo-bridged bis(imido) derivative are suitable molecular precursor materials for bulk molybdenum nitrides. Temperature-programmed thermolysis in flowing ammonia yields bulk molybdenum nitrides in high purity. The presence of ammonia facilitates complete hydrocarbon elimination resulting in products with carbon contents below 0.1 wt %. A maximum heating rate of 0.5 °C/min between 100 and 200 °C is necessary to prevent an explosive decomposition of these complexes. The resultant product at 700 °C is phase-pure δ-MoN, as characterized by XRD and elemental analysis. γ-Mo2N can be synthesized by simple variation of the thermolysis conditions: Annealing of the primary thermolysis product in inert gases (e.g., N2, Ar) from 500 to 700 °C decreases the nitrogen content, with γ-Mo2N resulting as the final phase. Oxygen contamination in the product, a major problem of common oxide-nitridation routes, is completely avoided by using this new synthetic approach." @default.
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- W2087514910 date "1998-05-15" @default.
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- W2087514910 title "Controlled Thermolysis of Nitrido- and Imidomolybdenum Complexes: A New Route to Phase-Pure Molybdenum Nitrides" @default.
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- W2087514910 doi "https://doi.org/10.1021/cm9800433" @default.
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