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• W2087519845 abstract "Ni(II) complexes of 5(3)-methylpyrazole-3(5)-carbohydrazide (MPCH) and its deprotonated anion (MPC) have been isolated and characterised in the solid state. Magnetic and electtronic spectral features classify both the bis-complexes Ni(MPCH)2X2·2H2O and the mono-chelates Ni(MPC)X·2H2O[X = Cl, Br, I, NO3, BF4, ClO4, SCN or 0.5SO4] as grossly octahedral ones. The IR spectra indicate that in the bis-derivatives the ligand is bidentate through the pyrazolyl-ring nitrogen and the kenotic oxygen of the hydrazide residue and that in the monochelates, the deprotonated ligand functions primarily as a (ONN) tridentate finally forming polymeric quasi-octahedral species through involvement of additional donor site (amide-nitrogen) of the hydrazide residue; the counterion (X) is coordinated in majority of the complex species." @default.
• W2087519845 created "2016-06-24" @default.
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• W2087519845 date "1981-01-01" @default.
• W2087519845 modified "2023-09-26" @default.
• W2087519845 title "Coordinating properties of a pyrazole-derived carbohydrazide, a potential ligand of biological importance: Ni(II) complexes of neutral and deprotonated 5(3)-methylpyrazole-3(5)-carbohydrazide" @default.
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• W2087519845 doi "https://doi.org/10.1016/0022-1902(81)80055-3" @default.
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