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- W2087526912 abstract "A global reduction theory of the vibration–rotational Hamiltonian of C3v closed-shell molecules, dealing with all possible anharmonic interactions in which a fundamental vibration can be involved, is presented. The effective correlation-free Hamiltonians and the corresponding matrix elements are derived. The cases studied here are (i) a fundamental band interacting with an overtone, (ii) a fundamental band interacting with a combination band. The Hamiltonian terms H30,H31,H32 and the recommended set of parameters following from the appropriate reductions are presented. The results are provided in a form directly applicable to the analysis of spectra of the interacting states." @default.
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- W2087526912 date "2015-05-01" @default.
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- W2087526912 title "Effective Hamiltonians for the Fermi resonance – Interacting states of <mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML altimg=si298.gif overflow=scroll><mml:mrow><mml:msub><mml:mrow><mml:mtext>C</mml:mtext></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mi>v</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math> molecules" @default.
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