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- W2087528698 abstract "The V–V fraction in HF self-relaxation is determined in fast-flow infrared chemiluminescence experiments through the consistent accounting of all HF(v) populations in partially relaxed mixtures. The v-level specific, fractional V–V probabilities fv are measured for v=2 and 3 using the F+H2 and F+CH4 generating reactions, and estimates are obtained for v=4 to 7 using F+HBr and H+F2 data. A consistent set of fv’s is 0.55±0.10, 0.30±0.10, 0.15±0.10, and zero for v=2, 3, 4, and 5 to 7, respectively. These values are compared with one recent laser measurement for v=2 and with the theoretical predictions of semiclassical trajectory calculations." @default.
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- W2087528698 date "1983-10-01" @default.
- W2087528698 modified "2023-10-16" @default.
- W2087528698 title "Vibrational relaxation of highly excited diatomics. V. The V–V channel in HF(<i>v</i>)+HF(0) collisions" @default.
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- W2087528698 doi "https://doi.org/10.1063/1.446237" @default.
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