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- W2087541387 abstract "The trans reduction of all types of alkynes to give (E)-olefins is achieved through a two-stage trans hydrosilylation and protodesilylation. Reaction of an alkyne and a silane with the ruthenium catalyst [Cp*Ru(MeCN)3]PF6 results in clean hydrosilylation to give only the (Z)-trans addition product at ambient temperature with catalyst loadings of 1-5 mol %. The crude vinylsilane products are then protodesilylated by the action of cuprous iodide and TBAF at rt-35 degrees C. The reaction is compatible with many sensitive functional groups and provides a general trans-alkyne reduction not possible by other means." @default.
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- W2087541387 date "2002-06-17" @default.
- W2087541387 modified "2023-09-27" @default.
- W2087541387 title "A Chemoselective Reduction of Alkynes to (<i>E</i>)-Alkenes" @default.
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- W2087541387 doi "https://doi.org/10.1021/ja026457l" @default.
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