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- W2087563206 abstract "A mild, stereoselective method for the Ni-catalyzed synthesis of alpha-C-alkylglycosides is reported. This approach entails the reductive coupling of glycosyl bromides with activated alkenes at room temperature, with low alkene loading as an important feature. Diastereoselective coupling with 2-substituted acrylate derivatives was made possible through the use of 2,4-dimethyl-3-pentanol as a proton source." @default.
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- W2087563206 date "2009-01-26" @default.
- W2087563206 modified "2023-09-23" @default.
- W2087563206 title "Sn-Free Ni-Catalyzed Reductive Coupling of Glycosyl Bromides with Activated Alkenes" @default.
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- W2087563206 doi "https://doi.org/10.1021/ol8028737" @default.
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