Matches in SemOpenAlex for { <https://semopenalex.org/work/W2087568883> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2087568883 endingPage "9996" @default.
- W2087568883 startingPage "9988" @default.
- W2087568883 abstract "The bromine-tetrathionate reaction has been studied in the presence of phosphoric acid/dihydrogen phosphate buffer at T = 25 +/- 0.1 degrees C and at I = 0.5 M ionic strength with both stopped-flow technique and a conventional diode array spectrophotometer. The stoichiometry of the reaction was found to be S4O(6)(2-) + 7Br2 + 10H2O --> 4SO(4)(2-) + 14Br- + 20H+ in bromine excess, but no unambiguous stoichiometry can be established in tetrathionate excess because elementary sulfur as well as hydrogen sulfide are also present in appreciable amounts besides the major product sulfate. It has also been shown that the reaction has two well-separable kinetic phases in an excess of tetrathionate. Rapid disappearance of bromine was observed in the early stage of the reaction followed by a much slower spectral change in the UV region that can be attributed to the disappearance of an absorbing species having much stronger light absorption than that of tetrathionate in the given wavelength range. Two different types of kinetic curves measured by two different instruments have been evaluated simultaneously that led us to suggest and discuss a 10-step model." @default.
- W2087568883 created "2016-06-24" @default.
- W2087568883 creator A5086408837 @default.
- W2087568883 creator A5090152714 @default.
- W2087568883 date "2009-08-20" @default.
- W2087568883 modified "2023-09-24" @default.
- W2087568883 title "Simultaneous Evaluation of Different Types of Kinetic Traces of a Complex System: Kinetics and Mechanism of the Tetrathionate−Bromine Reaction" @default.
- W2087568883 cites W1964768857 @default.
- W2087568883 cites W1973736552 @default.
- W2087568883 cites W1981731554 @default.
- W2087568883 cites W1982692685 @default.
- W2087568883 cites W1985337554 @default.
- W2087568883 cites W1999548171 @default.
- W2087568883 cites W2019538082 @default.
- W2087568883 cites W2020504635 @default.
- W2087568883 cites W2024282948 @default.
- W2087568883 cites W2024361784 @default.
- W2087568883 cites W2027860896 @default.
- W2087568883 cites W2040307728 @default.
- W2087568883 cites W2040956402 @default.
- W2087568883 cites W2047458728 @default.
- W2087568883 cites W2072225817 @default.
- W2087568883 cites W2074949133 @default.
- W2087568883 cites W2076984537 @default.
- W2087568883 cites W2080779398 @default.
- W2087568883 cites W2088694792 @default.
- W2087568883 cites W2091133867 @default.
- W2087568883 cites W2091474607 @default.
- W2087568883 cites W2094170110 @default.
- W2087568883 cites W2107680117 @default.
- W2087568883 cites W2121064474 @default.
- W2087568883 cites W2146842280 @default.
- W2087568883 cites W2150870892 @default.
- W2087568883 cites W2168774159 @default.
- W2087568883 cites W2324053077 @default.
- W2087568883 cites W2327936125 @default.
- W2087568883 cites W2332687082 @default.
- W2087568883 cites W2335607155 @default.
- W2087568883 cites W2346675510 @default.
- W2087568883 cites W2951366566 @default.
- W2087568883 cites W2952407937 @default.
- W2087568883 cites W4247483471 @default.
- W2087568883 doi "https://doi.org/10.1021/jp9026089" @default.
- W2087568883 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19694475" @default.
- W2087568883 hasPublicationYear "2009" @default.
- W2087568883 type Work @default.
- W2087568883 sameAs 2087568883 @default.
- W2087568883 citedByCount "8" @default.
- W2087568883 countsByYear W20875688832012 @default.
- W2087568883 countsByYear W20875688832017 @default.
- W2087568883 countsByYear W20875688832019 @default.
- W2087568883 countsByYear W20875688832023 @default.
- W2087568883 crossrefType "journal-article" @default.
- W2087568883 hasAuthorship W2087568883A5086408837 @default.
- W2087568883 hasAuthorship W2087568883A5090152714 @default.
- W2087568883 hasConcept C144082473 @default.
- W2087568883 hasConcept C178790620 @default.
- W2087568883 hasConcept C179104552 @default.
- W2087568883 hasConcept C185592680 @default.
- W2087568883 hasConcept C194191183 @default.
- W2087568883 hasConcept C2776062316 @default.
- W2087568883 hasConcept C2780564542 @default.
- W2087568883 hasConcept C2780596425 @default.
- W2087568883 hasConcept C2781090017 @default.
- W2087568883 hasConcept C517835270 @default.
- W2087568883 hasConcept C518881349 @default.
- W2087568883 hasConceptScore W2087568883C144082473 @default.
- W2087568883 hasConceptScore W2087568883C178790620 @default.
- W2087568883 hasConceptScore W2087568883C179104552 @default.
- W2087568883 hasConceptScore W2087568883C185592680 @default.
- W2087568883 hasConceptScore W2087568883C194191183 @default.
- W2087568883 hasConceptScore W2087568883C2776062316 @default.
- W2087568883 hasConceptScore W2087568883C2780564542 @default.
- W2087568883 hasConceptScore W2087568883C2780596425 @default.
- W2087568883 hasConceptScore W2087568883C2781090017 @default.
- W2087568883 hasConceptScore W2087568883C517835270 @default.
- W2087568883 hasConceptScore W2087568883C518881349 @default.
- W2087568883 hasIssue "37" @default.
- W2087568883 hasLocation W20875688831 @default.
- W2087568883 hasLocation W20875688832 @default.
- W2087568883 hasOpenAccess W2087568883 @default.
- W2087568883 hasPrimaryLocation W20875688831 @default.
- W2087568883 hasRelatedWork W1521482935 @default.
- W2087568883 hasRelatedWork W1967034448 @default.
- W2087568883 hasRelatedWork W1980315180 @default.
- W2087568883 hasRelatedWork W1982210809 @default.
- W2087568883 hasRelatedWork W2087568883 @default.
- W2087568883 hasRelatedWork W2162325017 @default.
- W2087568883 hasRelatedWork W2777306736 @default.
- W2087568883 hasRelatedWork W3022031989 @default.
- W2087568883 hasRelatedWork W325023061 @default.
- W2087568883 hasRelatedWork W98014425 @default.
- W2087568883 hasVolume "113" @default.
- W2087568883 isParatext "false" @default.
- W2087568883 isRetracted "false" @default.
- W2087568883 magId "2087568883" @default.
- W2087568883 workType "article" @default.