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- W2087574927 abstract "The standard (po = 0.1 MPa) molar enthalpies of combustion in oxygen at 298.15 K were measured by static-bomb calorimetry for succinic anhydride, glutaric anhydride, and glutarimide. The standard molar enthalpies of sublimation of these compounds were derived from vapour pressures as functions of temperature determined using Knudsen cells in a microcalorimeter. −ΔcHmo(cr)/(kJ·mol−1)ΔcrgHmo/(kJ·mol−1)Succinic anhydride1537.1±0.480.7±1.6Glutaric anhydride2206.5±0.486.1±1.6Succinimide83.6±1.5Glutarimide2480.3±0.594.1±1.6 From the standard molar enthalpies of formation in the gaseous state it was deduced that the conventional strain-energies in the six-membered-ring compounds, glutaric anhydride and glutarimide, are greater than in the corresponding five-membered-ring compounds, succinic anhydride and succinimide." @default.
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- W2087574927 date "1990-09-01" @default.
- W2087574927 modified "2023-10-14" @default.
- W2087574927 title "Enthalpies of combustion of succinic anhydride, glutaric anhydride, and glutarimide" @default.
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- W2087574927 doi "https://doi.org/10.1016/0021-9614(90)90177-r" @default.
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