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- W2087577498 abstract "Crystallographic and spectroscopic investigations were carried out for Cu(II) complexes of 15-crown-5 (15C5) and 4′-substituted benzo-15-crown-5 (B15C5) derivatives. X-Ray diffraction measurements were performed for two single crystals of [Cu(15C5)(H2O)2](ClO4)2 and [Cu(B15C5)(H2O)2](ClO4)2, obtained from 60% HClO4 solutions. The results of the X-ray analysis demonstrated that these complexes take a seven-coordinate pentagonal bipyramidal geometry, in which the copper ion is located in the center of the crown ether cavity with two water molecules at the axial positions. The ESR spectra observed for these complexes in 60% HClO4 exhibited the characteristic g-anisotropy (gz < gx, gy), leading to an electronic configuration of a 3dz2 ground-state doublet. ESR and electronic absorption measurements were made for Cu(II) complexes of 4′-substituted B15C5 in systems of BF3–ether–water and of dry CHCl3 in which complexes having two chloride ions at the axial positions were produced. Although these systems showed ..." @default.
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- W2087577498 date "1996-09-01" @default.
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- W2087577498 title "X-Ray Structures and Spectroscopic Studies of Diaqua- and Dichlorocopper(II) Complexes of 15-Crown-5 and 4′-Substituted Benzo-15-Crown-5 with a 3d<sub>z<sup>2</sup></sub>Ground-State Doublet" @default.
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- W2087577498 doi "https://doi.org/10.1246/bcsj.69.2513" @default.
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