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- W2087581526 abstract "It is shown that the criteria of space filling expressed by v = φVc/Vw = constant [where φ, Vc and Vw are the concentration, the volume of the coil containing the random chain of mass M and the Van der Waals volume of that chain] gives the onset of entanglements in linear and branched melts and in concentrated polymeric solutions (Cornet criteria). In binary melts, containing long and short chains of length N and N0, this criterion applied to the equivalent chain N/N0 gives the experimental concentration φc above which the long chains are “entangled”, It is emphasized that the notion of entanglement is a relative one This space filling criteria is compared to the other criteria found in the literature." @default.
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- W2087581526 date "1987-01-01" @default.
- W2087581526 modified "2023-10-02" @default.
- W2087581526 title "Space filling and entanglements in polymeric systems" @default.
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- W2087581526 doi "https://doi.org/10.1016/0377-0257(87)80020-4" @default.
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