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- W2087588881 abstract "Methyl acrylate is readily polymerised by the CpTiCl3–MAO system. A kinetic study shows that the reaction is characterised by a linear dependence of the rate upon methyl acrylate concentration, and by saturation behaviour with respect to both catalyst CpTiCl3 and co-catalyst MAO. The kinetic behaviour is interpreted in terms of insertion of an O-complexed monomer into a η3 enolate-Ti growing polymer chain. When a mixed methyl acrylate–styrene monomer system is used, a mechanism resulting in a much slower formation of a random 1:1 co-polymer is proposed." @default.
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- W2087588881 date "2005-05-01" @default.
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- W2087588881 title "Kinetics and mechanism of methyl acrylate homo- and co-polymerisation catalysed by cyclopentadienyltitanium trichloride–MAO" @default.
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- W2087588881 doi "https://doi.org/10.1016/j.molcata.2005.01.032" @default.
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