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- W2087599690 abstract "The dilithiated derivative 2 of 1,1′-bis(trimethylsilylamino)ferrocene (1) reacts with the pyridine adducts of the aluminum trihalides AlX3 (X = Cl, Br, I) to give the respective 1,3,2-diazaalumina-[3]ferrocenophanes (4b, c, d) as pyridine adducts. The fluoride 4a could not be obtained in this way. The reaction of 1,1′-bis(trimethylsilylamino)ferrocene (1) with the dimethyl(ethyl)amine- or pyridine adduct of aluminium trihydride gave the 1,3,2-diazaalumina-[3]ferrocenophanes (5) and (6) as the amine and pyridine adducts, respectively. Treatment of 5 with trimethyltin fluoride afforded the adduct 7 with an Al–F function. Addition of pyridine converted 7 into the desired pyridine adduct of the fluoride (4a). The molecular structures of the pyridine adducts 4a, 4b, 4c and 6 were determined by X-ray analysis. The pyridine is in the trans-position relative to the N–Si bond vectors, and temperature dependent solution-state NMR spectra prove that prominent structural features are retained in solution." @default.
- W2087599690 created "2016-06-24" @default.
- W2087599690 creator A5029446593 @default.
- W2087599690 creator A5044451653 @default.
- W2087599690 creator A5079183378 @default.
- W2087599690 date "2007-08-01" @default.
- W2087599690 modified "2023-10-18" @default.
- W2087599690 title "Novel diaminoaluminum halides and a diaminoaluminum hydride: 1,3,2-Diazaalumina-[3]ferrocenophanes" @default.
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- W2087599690 doi "https://doi.org/10.1016/j.poly.2007.03.035" @default.
- W2087599690 hasPublicationYear "2007" @default.
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